The chemicals and the reaction conditions required for the prepar

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 Multiple Choice QuestionsMultiple Choice Questions

91.

What is Y in the following reaction?

C2H5I + NaOC2H5 → X + NaI

X + 2HHI  2Y + H2O

  • C2H6

  • C2H5I

  • C2H4

  • C2H5OC2H5


92.

Consider the following reaction,

C6H5NO2 Sn/ HCl X C6H5COCl Y + HCl

What is Y?

  • Acetanilide

  • Benzanilide

  • Azo-benzene

  • Hydrazo-benzene


93.

Nitrating mixture is

  • fuming nitric acid

  • mixture of conc H2SO4 and conc HNO3

  • mixture of nitric acid and anhydrous zinc chloride

  • None of the above


94.

Consider the following reactions:

X + HCl (Addition)Anhydrous AlCl3 C2H5Cl                                       (Substitution)Ahydrous ZnCl2/ HCl Y

Y can be conserted to X on heating with ....... at ...... temperature :

  • Al2O3, 350°C

  • Cu, 300°C

  • Ca(OH)2+ CaOCl2, 60°C

  • NaOH/I2, 60°C


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95.

When acetylene is passed through red hot iron tube, compound X is formed. Which one  of the  following reactions will yield X as the major product?

  • C6H5OH +Zn Distillation

  • C6H5SO3H +NaHCO3 

  • C6H12 + 3H2 Ni

  • C6H5Cl + H2O 


96.

2, 3-dimethyl hexane contains...... tertiary ....... secondary and ......  primary carbon atoms, respectively:

  • 2,2,4

  • 2,4,3

  • 4,3,2

  • 3,2,4


97.

Which of the following reactions proceeds via a secondary free radical?

  • CH3-CH=CH2 HBr CH3-CHBr-CH3

  • CH3-CH=CH2 UV light HBr CH3-CH2-CH2Br

  • C6H6 Br2/FeBr3 C6H5Br

  • C6H6 UV light Br2 CH3-Br2


98.

4 g of a hydrocarbon on complete combustion gave 12.571 g of CO2 and 5.143 g of water. What is the empirical formula of the hydrocarbon ?

  • CH

  • CH2

  • CH3

  • C2H3


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99.

The chemicals and the reaction conditions required for the preparation of ethane are

  • C2H5I, Zn-Cu, C2H5OH

  • CH3Cl, Na, H2O

  • KOOC-CH=CH-COOK, , electrolysis

  • CH3CO2Na, NaOH, CaO, Δ


A.

C2H5I, Zn-Cu, C2H5OH

Alkyl halides can be reduced to hydrocarbons by means of Zn-Cu couple in presence of alcohol.

 C2H5I C2H5OH Zn-Cu C2H6 Ethane + HI


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100.

What is the molecular formula of the product formed when benzene is reacted with ethyl chloride in presence of anhydrous aluminium chloride?

  • C8H10

  • C6H6

  • C8H8

  • C6H5Cl


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