In which of the following, ortho/para substitution by an electrop

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 Multiple Choice QuestionsMultiple Choice Questions

101.

The metal used for the de-brommation reaction of 1, 2-dibromoethane

  • Na

  • Zn

  • Mg

  • Li


102.

Which of the following reagents when heated with ethyl chloride, forms ethylene ?

  • Aqueous KOH

  • Zn/ HCl

  • Alcoholic KOH

  • HI


103.

Which of the following compounds is soluble in benzene but almost insoluble in water?

  • C2H5OH

  • CH3CO2H

  • CH3CHO

  • C6H5NO2


104.

The compound prepared by a substitution reaction of benzene is

  • acetophenone

  • glyoxal

  • cyclohexane

  • hexabromo cyclohexane


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105.

The number of sigma (σ) and pi (π) bonds present in benzene respectively are :

  • 12, 6

  • 6, 6

  • 6, 12

  • 12, 3


106.

Identify 'B in the following reaction CH2=CH2 + HCl anhy AlCl3 A + 2[H] C2H5OHZn-Cu B + HCl

  • CH4

  • C2H6

  • C2H5Cl

  • C2H5OH


107.

Which of the following compound(s) has 'Z' configuration ?

  • (i) only

  • (ii) only

  • (iii) only

  • (i) and (iii) only


108.

The structure of the compound formed, when nitrobenzene is reduced by lithium aluminium hydride (LiAlH4) is


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109.

Diels-Alder reaction will not take place with which of the following reactants?


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110.

In which of the following, ortho/para substitution by an electrophile is very facile?

  • Ntrobenzene

  • Phenol

  • Benzoic acid 

  • Acetophenone


B.

Phenol

-OH group is ortho/para directing and makes the benzene ring more active towards electrophilic substitution. Thus, ortho/para substituton m phenol by an electrophile is very facile.


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