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141.

The strongest ortho/para directing group is

  • -NH2

  • -CH3

  • -Cl

  • -C2H5


A.

-NH2

All those groups which contain at least one pair of non-bonding electrons on the atom adjacent to the benzene ring, are ortho and para directing. Among the given options, all are ortho and para directing but their capacity of ortho-para direction on follows the order.

-N..H2 > -CH3 > -C2H5 >-Cl

Hence, -N..H2 is the strognest ortho-para direction group.


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142.

An organic alkadiene on reductive ozonolysis produces
(i) acetaldehyde
(ii) acetone
(iii) 2-methylpropane-1,3-dial
The formula of alkadiene will be

  • CH3C(CH3)=CHCH(CH3)CH=CHCH3

  • CH3CH(CH3)CH=C(CH3)CH=CHCH3

  • CH3C(CH3)=CHCHC(CH3)=CHCH3

  • CH3CH2CH(CH3)CH=CHC(CH3)=CH2


143.

2-chloro-3-methylbutane is treated with sodium in etherial solution, then it will give

  • 2,4-dimethylhexane

  • 3,5-dimethylhexane

  • 2,3,4,5-tetramethylhexane

  • 2,6-dimethyloctane


144.

Which one of the following hydrocarbons has octane number 100?

  • 2, 2, 3-trimethylpentane

  • 2, 3, 3-trimethylpentane

  • 2, 2, 4-trimethylpentane

  • 2, 3, 4-trimethylpentane


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145.

Which one of the following is the best reagent to accomplish the following conversion ?

CH3CH2Br ? CH3-CH3

  • NaBH3

  • Na|ether

  • Zn|C2H5OH

  • Mg followed by H3O+


146.

Benzene has the following hybridisation

  • sp

  • sp2

  • sp3

  • dsp2


147.

Propyne and propene can be distinguished by

  • conc. H2SO4

  • Br2 in CCl4

  • dil. H2SO4

  • AgNO3 in ammonia


148.

C2H5Cl CuILi C2H5Cl n-butane. This method is

  • Wurtz synthesis

  • Kolbe synthesis

  • Corey House synthesis

  • Friedel-Craft synthesis


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149.

One of the isomer of the 5th member of alkyne series is optically active. It is

  • 4-methyl pent-2-yne

  • 3-methyl pent-1-yne

  • 4-methyl pent-1-yne

  • 3, 3-dimethyl but-1-yne


150.

Which compound present in diesel?

  • Cetane

  • TiCl4

  • Cyclo pentandenyl manganese carbonyl

  • Iso octane


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