CH3CH2C≡CH⇌BA CH3C≡C-CH3, A and B are fro

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 Multiple Choice QuestionsMultiple Choice Questions

151.

Acetylene and HCHO react in presence of copper acetylide catalyst to form

  • But-2-yne-1, 2-diol

  • But-1-yne-1, 4-diol

  • But-2-ene-1, 4-diol

  • 2-butyne-1, 4-diol


152.

Which of the following substance is not related with HVZ reaction?

  • α-bromo acetic acid

  • Zn/ Hg

  • Cl2

  • Red P


153.

Which of the following compound show acidic nature?

  • but-1-yne

  • but-2-yne

  • but-1-ene

  • buta-1, 3-diene


154.

Compound A on ozonolysis gives acetone and glyoxal. The compound A is

  • 2, 5-dimethyl hex-2, 4-dene

  • 2, 5-dimethyl hex-1, 5-diene

  • 2, 5-dimethyl hex-3, 4-diene

  • 2, 5-dimethyl but-2, ene


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155.

CH3CH2CCHBA CH3CC-CH3, A and B are

  • alc KOH and SeO2

  • NaNH2 and lindlar catalyst

  • alc KOH and NaNH2

  • Lindlar catalyst and NaNH2


C.

alc KOH and NaNH2

CH3CH2CCH BA CH3-CC-CH3CH3CH2CCH Ethanolic KOH[CH3CH=C=CH2]Intermediate  CH3CCCH3but-2-yne

Acetylene homologues isomense when heated with ethanohc KOH, the triple bond moving towards the centre of the chain.

CH3CCCH3 (ii) H+(i) NaNH2 paraffin CH3-CH2CCH

When alkynes are heated with sodamide in an inert solvent [paraffin), triple bond shifts
towards the end of the chain.


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156.

Tetrabromoethane on heating with Zn gives

  • ethyl bromide

  • ethane

  • ethyne

  • ethene


157.

Which compound does not form 2-methyl but-2-ene on heating with alc. KOH?

  • 1-bromo-2 methyl propane

  • 2-bromo-3-methyl butane

  • 2-bromo-2-methyl butane

  • None of the above


158.

In the reaction,

Acetylene NH4ClCuCl H2C=CH-CCHLindlar's catalyst(Pd/CaCO3)A

The final product A is:

 

  • butene

  • butyne-2

  • butyne-1

  • buta-1, 3-dene


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159.

The olefin which on ozonolysis gives CH3CH2CHO and CH3CHO is

  • 2-butene

  • 1-pentene

  • 1-butene

  • 2-pentene


160.

Which one of the following alkenes will react faster with H2 under catalytic hydrogenation conditions?


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