Which of the following is not correct regarding the elecolytic pr

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91.

Which of the following is not correct regarding the elecolytic preparation of H2O2?

  • Lead is used as cathode

  • 50% H2SO4 is used

  • Hydrogen is liberated at anode

  • Sulphuric acid undergoes oxidation


C.

Hydrogen is liberated at anode

H2O2 can be prepared by electrolysis of 50% H2SO4. In this method, hydrogen is liberated at cathode.

H2SO4 2H+ 2HSO4-

At anode - 2HSO4- H2S2O8 + 2e-

H2S2O8 + 2H22H2SO4 + H2O2

At cathode - 2H+ + 2e- H2 


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92.

What are the values of n1 and n2 respectively for Hβ line in the Lyman series of hydrogen atomic spectrum 44 ?

  • 3 and 5

  • 2 and 3

  • 1 and 3

  • 2 and 4


93.

The most probable velocity (in cm/s) of hydrogen molecule at 27°C will be

  • 19.3 x 104

  • 17.8 x 104

  • 24.93 x 109

  • 17.8 x 108


94.

Heavy water is

  • CaSO4

  • water contain CaSO4, MgSO4

  • D2O

  • water contain CaCO3


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95.

The number of moles of oxygen obtained by the electrolytic decomposition of 108 g water is

  • 2.5

  • 3

  • 5

  • 7.5


96.

Presence of phosphoric acid or glycerine or acetanilide retards the decomposition of H2O.This is an example of:

  • Positive catalysis.

  • Negative catalysis.

  • Auto catalysis.

  • Induced catalysis.


97.

For binary hydrides of formula M x n the value of n can be fractional for:

  • salt like hydrides

  • interstitial hydrides

  • covalent hydrides

  • polymeric hydrides


98.

The reaction of HBr with  in the presence of peroxide will give

  • CH3CH2CH2CH2Br


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99.

Hardness of water is due to presence of salts of:

  • Naand K+

  • Ca2+ and Mg2+

  • Ca2+ and K+

  • Ca2+ and Na+


100.

H2O is liquid while H2S is a gas due to

  • covalent bonding

  • molecular attraction

  • H-bonding

  • both H-bonding and molecular attraction


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