Assertion : Increasing pressure on pure water decreases its freez

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 Multiple Choice QuestionsMultiple Choice Questions

121.

Assertion : Compressibility factor for hydrogen varies with pressure with positive slope at all pressures.

Reason : Even at low pressures, repulsive forces dominate hydrogen gas.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


122.

The reagent commonly used to determine hardness of water titrimetrically is

  • oxalic acid

  • disodium salt of EDTA

  • sodium citrate

  • sodium thiosulphate


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123.

Assertion : Increasing pressure on pure water decreases its freezing point.

Reason : Density of water is minimum at 273 K.

  • If both assertion and reason are true and the reason is the correct explanation of the assertion.

  • If both assertion and reason are true and the reason is not the correct explanation of the assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


B.

If both assertion and reason are true and the reason is not the correct explanation of the assertion.

According to Clapeyron-Clausius equation,

dTdP = T(Vl - Vs)Hf

Since density of ice is less than that of water, Vs is greater than V(the expression on the right hand side of the equation is negative). It means that the increase of pressure must lower the freezing point and decrease of pressure must raise the freezing point.


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124.

Assertion : The micelle formed by sodium stearate in water has - COO- groups at the surface.

Reason : Surface tension of water is reduced by the addition of stearate.

  • If both assertion and reason are true and the reason is the correct explanation of the assertion.

  • If both assertion and reason are true and the reason is not the correct explanation of the assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


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125.

When H2O2 is shaken with an acidified solution of K2Cr2O7 in the presence of ether, the ethereal layer turns blue due to the formation of:

  • Cr2O3

  • CrO42-

  • Cr2(SO4)3

  • CrO5


126.

Commercial sample of H2O2 is labeled as 10 V. Its % strength is nearly

  • 3

  • 6

  • 9

  • 12


127.

The reagent with which the following reaction is best accomplished is

  • H3PO2

  • H3PO3

  • H3PO4

  • NaHSO3


128.

The order of decreasing ease of abstraction of hydrogen atoms in the following molecule

  • Ha > Hb > Hc

  • Ha > Hc > Hb

  • Hb > Ha > Hc

  • Hc > Hb > Ha


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129.

In the hydrolysis of an organic chloride in presence of large excess of water

RCl + H2O → ROH + HCl

  • molecularity and order of reaction both are 2

  • molecularity is 2 but order of reaction is 1

  • molecularity is 1 but order of reaction is 2

  • molecularity is 1 but order of reaction is also 1


130.

Ortho and para hydrogens have

  • Identical chemical properties but different physical properties 

  • Identical physical and chemical properties 

  • Identical physical properties  but different chemical properties 

  • Different chemical and physical properties 


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