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 Multiple Choice QuestionsMultiple Choice Questions

161.

Osmotic pressure of the solution can be increased by,

  • increasing the temperature of the solution

  • decreasing the temperature of the solution

  • increasing the volume of the vessel

  • diluting the solution


162.

After adding non-volatile solute freezing point of water decreases to -0.186C. Calculate ΔTb if Kf = 1.86 K kg mol-1 and Kb =0.521 K kg mol-1.

  • 0.521

  • 0.0521

  • 1.86

  • 0.0186


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163.

Which of the following has the lowest freezing point?

  • 0.1 m sucrose

  • 0.1 m urea

  • 0.1 m ethanol

  • 0.1 m glucose


C.

0.1 m ethanol

Depression in freezing is colligative property. More the number of ions of solute more will be depression in freezing point and hence lower melting point.

(i) 0.1 m sucrose, 0.1 m urea and 0.1 m glucose are non-electrolytes. They do not dissociate.

(ii) In 0.1 methanol, ethanol dissociates into C2H5O- and H+ ions. So it has highest number of ions among given choices.

Therefore, 0.1 m ethanol has lowest freezing point.


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164.

A litre of solution is saturated with AgCl. To this solution if 1.0 × 10-4 mole of solid NaCl is added, what will be the [Ag+], assuming no volume change ?

  • More

  • Less

  • Equal

  • Zero


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165.

The vant Hoffs factor 'i' accounts for

  • extend of solubility

  • extent of mobility of solute

  • extent of dissolution of solute

  • extent of dissociation of solute


166.

When the pure solvent diffuses out of the solution through the semi-permeable membrane then the process is called

  • sorption

  • dialysis

  • reverse osmosis

  • osmosis


167.

Which has the minimum freezing point ?

  • One molal NaCl aq. solution

  • One molal CaCl2 aq. solution

  • One molal KCl aq. solution

  • One molal urea aq. solution


168.

Which of the following aqueous solution has highest freezing point?

  • 0.1 molal Al2(SO4)3

  • 0.1 molal BaCl2

  • 0.1 molal AlCl3

  • 0.1 molal NH4Cl


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169.

If a solution containing 0.072 g atom of sulphur in 100 g of a solvent (kf = 7.0) gave a freezing point depression of 0.84°C, the molecular formula of sulphur in the solutions is :

  • S6

  • S7

  • S8

  • S9


170.

Which one of the following is not correct for an ideal solution ?

  • It must obey Raoult's law

  • H = 0

  • C = 0

  • H = V  0


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