Assertion : Azeotropic mixtures are formed only by non-ideal solu

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 Multiple Choice QuestionsMultiple Choice Questions

261.

The average molar heat capacity at constant volume of gaseous mixture contained 2 moles of each of two ideal gases X (CV , m = 32R) and Y (CV , m = 52R)

  • 2R

  • 3R

  • 4R

  • 8R


262.

How many grams of CaC2O4 will dissolve in distilled water to make one litre of saturated solution? Solubility product of CaC2O4 is 2.5 x 10-9 mol2 litre-2 and its molecular weight is 128

  • 0.0640 gm

  • 0.0032 gm

  • 0.0128 gm

  • 0.0064 gm


263.

1 g of a non-volatile, non-electrolyte solute of molar mass 250 g/mol was dissolved in 51.2 g of benzene. If the freezing point depression constant , kf of benzene is 5.12 kg K mol-1 , the freezing point of benzene is lowered by :

  • 0.3 K

  • 0.5 K

  • 0.2 K

  • 0.4 K


264.

A 6% solution of urea is isotonic with :

  • 1M solution of glucose

  • 0.05 M solution of glucose

  • 6% solution of glucose

  • 25% solution of glucose


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265.

In countries nearer to polar region, the roads are sprinkled with CaCl2 .This is :

  • to minimise the wear and tear of the roads

  • to minimise the snow fall

  • to minimise pollution

  • to minimise the accumulation of dust on the road


266.

The solubility of a gas in water at 300 K under a pressure of 100 atm is 4 x 10-3 kg L-1. Therefore, the mass of the gas in kg dissolved 250 mL of water under a pressure of 250 atm at 300 K is :

  • 2.5 x 10-3

  • 2.0 x 10-3

  • 1.25 x 10-3

  • 5.0 x 10-3


267.

The depression in freezing point of 0.1 M aqueous solutions of HCl, CuSO4 and K2SO4 are in the ratio

  • 1 : 1 : 1.5

  • 1 : 2 : 3

  • 1 : 1 : 1

  • 2 : 4 : 3


268.

Which of the following pairs of substances cannot exist together in solution?

  • Na2CO3 + NaOH

  • NaHCO3 + Na2CO3

  • NaHCO3 + NaOH

  • NaOH + HCl


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269.

Assertion : Azeotropic mixtures are formed only by non-ideal solutions and they may have boiling points either greater than both the components or lesser than both the components.

Reason : The composition of the vapour phase is same as that ofthe liquid phase of an azeotropic mixture.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false

  • If both assertion and reason are false.


B.

If both assertion and reason are true but reason is not the correct explanation of assertion.

Non-ideal solutions with positive deviation i.e., having more vapour pressure than expected, boil at lower temperature while those with negative deviation boil at higher temperature than those of the components.


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270.

Large difference in boiling points is observed in

  • N and P

  • P and As

  • As and Sb

  • Sb and Bi


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