The volume-temperature graphs of a given mass of an ideal gas at

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91.

The volume-temperature graphs of a given mass of an ideal gas at constant pressures are shown below. What is the correct order of pressures?

  • P1 > P3 > P2

  • P1 > P2 > P3

  • P2 > P3 > P1

  • P2 > P1 > P3


A.

P1 > P3 > P2

The correct order of pressure is P1 > P3 > P2.


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92.

When 25 g of a non-volatile solute is dissolved in 100 g of water, the vapour pressure is lowered by 2.25 × 10-1 mm. If the vapour pressure of water at 20°C is 17.5 mm, what is the molecular weight of the solute ?

  • 206

  • 302

  • 350

  • 276


93.

A certain mass of a gas occupies a volume of 2L at STP. To what temperature the gas must be heated to double its volume, keeping the pressure constant ?

  • 100 K

  • 273 K

  • 273°C

  • 546°C


94.

The average kinetic energy of one molecule of an ideal gas at 27°C and 1 atm pressure is

  • 900 cal K-1 mol-1

  • 6.21 × 10-21 JK-1 molecule-1

  • 336.7 JK-1 molecule-1

  • 3741.3 JK-1 mol-1


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95.

CH4 diffuses two times faster than a gas X. The number of molecules present in 32 g ofgas X is (N is Avogadro number)

  • N

  • N/2

  • N/4

  • N/16


96.

Under which one of the following conditions do real gases approach the ideal gas behaviour?

  • Low temperature and high pressure

  • High temperature and high pressure

  • High temperature and low pressure

  • Low temperature and low pressure


97.

Which one of the following is the ratio of the lowering of vapour pressure of 0.1 M , aqueous solutions of BaCl2, NaCl and Al2SO3 respectively?

  • 3 : 2 : 5

  • 5 : 2 : 3

  • 5 : 3 : 2

  • 2 : 3 : 5


98.

Which one of the following equations represents the variation of viscosity coefficient (η) with temperature (T)?

  • η= Ae-E/RT

  • η= AeE/RT

  • η= Ae-E/kT

  • η= Ae-E/T


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99.

Assertion (A): van der Waals' forces are reponsible for chemisorptions.

Reason (R): High temperature is favourable for chemisorptions.

The correct answer is:

  • (A) is false, but (R) is true

  • Both (A) and (R) are correct and (R) is the correct explanation of A

  • Both (A) and (R) are correct and (R) is not the correct explanation of (A)

  • (A) is true, but (R) is false


100.

Which one of the following is the wrong statement about the liquid?

  • It has intermolecular force of attraction.

  • Evaporation of liquids increase with the decrease of surface area.

  • It resembles a gas near the cnt1cal temperature.

  • lt is an intermediate state between gaseous and solid state.


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