Which one of the following defects in the crystals lowers its den

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 Multiple Choice QuestionsMultiple Choice Questions

91.

Which statement is not true for metals?

  • They form bcc structure

  • They form hcp structure

  • They form ccp structure

  • They have low enthalpy of sublimation


92.

How many crystal system are there when a≠b ≠c and a = b= c?

  • 2,3

  • 3,4

  • 4,3

  • 3,2


93.

The cubic unit cell of a metal (molar mass = 63.55g mol-1) has an edge length of 362 pm. Its density is 8.92 g cm-3 . The type of unit cell is

  • primitive

  • face- centred

  • body centred

  • end centred


94.

The flame colours of metal ions are due to

  • Frenkel defect

  • Schottky defect

  • Metal deficiency defect

  • Metal excess defect


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95.

Which one of the following statements about amorphous solids is incorrect?

  • They melt over a range of temperature

  • They are anisotropic

  • There is no orderly arrangement of particles

  • They are rigid and incompressible


96.

If the distance between Na+ and Cl- ionsin sodium chloride crystal is X pm, the length of the edge of the unit cell is

  • 4X pm

  • X/4 pm

  • X/2 pm

  • 2 X pm


97.

Which of the following does not conduct electricity?

  • Fused NaCl

  • Solid NaCl

  • Brine solution

  • Copper


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98.

Which one of the following defects in the crystals lowers its density?

  • Frenkel defect

  • Schottky defect

  • F-centres

  • Interstitial defect


B.

Schottky defect

Schottky defects are due to vacancy at a cation site accompanied by vacancy at an anion site so that the electrical neutrality of the system is maintained. Due to this defect, density decreases.


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99.

The radii of Na+ and Cl- ions are 95 pm and 181 pm respectively. The edge length of NaCl unit cell is :

  • 276 pm

  • 138 pm

  • 552 pm

  • 415 pm


100.

Malleability and ductility of metals can be accounted due to

  • the presence of electrostatic force

  • the crystalline structure in metal

  • the capacity of layers of metal ions to slide over the other

  • the interaction of electrons with metal ions in the lattice


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