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 Multiple Choice QuestionsMultiple Choice Questions

281.

The properties of Zr and Hf are same because :

  • they have similar radii

  • they belong to d-block

  • they have same valence electrons

  • None of the above


282.

Formation of coloured solution is possible when metal ion in the compound contains :

  • paired electrons

  • lone pair of electrons

  • unpaired electrons

  • None of the above


283.

In the periodic table metals usually used as catalysts belong to :

  • f - block

  • d - block

  • p - block

  • s - block


284.

In a neutron induced reaction of U92235 , the product obtained is Rb3795 , three neutrons and an element (new nuclide) .The other new nuclide is :

  • Cs55138

  • Ba56140

  • Xe54144

  • Sr3890


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285.

The electronic configuration of Cr3+ is :

  • [Ar] 3d4 4s2

  • [Ar] 3d3 4s0

  • [Ar] 3d2 4s1

  • [Ar] 3d5 4s1


286.

The lanthanide contraction is responsible for the fact that :

  • Zr and Zn have the same oxidation state

  • Zr arid Hf have about the same radius

  • Zr and Nb have similar oxidation state

  • Zr and Y have about the same radius


287.

Which of the following forms a colourless solution in aqueous medium ?

  • Cr3+

  • V3+

  • Sc3+

  • Ti3+


288.

The atomic number of Ni and Cu are 28 and 29 respectively .The electronic configuration 1s , 2s2 2p6 , 3s2 3p6 3d10 represents :

  • Cu+

  • Cu2+

  • Ni2+

  • Ni


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289.

Assertion : Transition metals are poor reducing agents.

Reason : Transition metals form numerous alloys
with other metals.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


B.

If both assertion and reason are true but reason is not the correct explanation of assertion.

In actual practice transition metals react with acid very slowly and act as poor reducing agents. This is due to the protection of metal as a result of formation of thin oxide protective film. Further, their poor tendency as reducing agent is due to high ionisation energy, high heat of vapourization and low heat of hydration.


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290.

Assertion : The degree of complex formation in actinides decreases in the order M4+ > MO22+ > M3+ > MO2+.

Reason : Actinides form complexes with p-bonding ligands such as alkyl phosphines and thioethers.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


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