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 Multiple Choice QuestionsMultiple Choice Questions

401.

Aqueous solution of Na2SO3 on reaction with Cl2 gives

  • Na2S4O6

  • NaOH

  • NaHSO4

  • NaCl


402.

The electronic configuration of P in H3PO4

  • 1s2 2s2, 2p6, 3s2 3p6

  • 1s2, 2s2, 2p6 3s2

  • 1s2, 2s2 2p6

  • 1s2, 2s2, 2p6,3s2 3p3


403.

In which one of the following reactions, nitrogen is not reduced?

  • NO2 → NO2-

  • NO3-  NO

  • NO3- NH4+

  • NH4+  N2


404.

Which of the following metal is leached by cyanide process?

  • Na

  • Cu

  • Ag

  • Fe


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405.

The correct order of electron gain enthalpy with negative sign is

  • S <O <Cl < F

  • O <S < F < Cl

  • Cl <F <S <O

  • F <Cl <O < S


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406.

Which gas behaves abnormally when liquified?

  • Xenon

  • Krypton

  • Helium

  • Argon


C.

Helium

The ease of liquefaction of a gas depends upon the magnitude of the attractive forces present in its atoms or molecules and He being smallest molecules among all the noble gases, the intermolecular forces of attraction in them are negligible.

Weaker are the intermolecular forces, more difficult it is to liquify that gas and lower would be the critical temperature of that gas.

Tc for helium = 5.2 K (the temperature above which it cannot be liquified however high pressure may be applied on the gas).

This is why when natural gas is compressed to about 100 atm and could to 78 K, helium does not liquify while all other gases get liquified. Thus, helium has lowest critical temperature (5.2 K) among all known gases.


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407.

Which statement is false for white phosphorus (P4)?

  • It has six P-P single bonds

  • It has four P-P single bonds

  • It has four lone pairs of electrons

  • It has PPP angle 60°


408.

Match List I (species) with List II (hybridization) and select the correct code given below

 

  List I  List II
A. XeF4 (i) dsp2
B. H2O (ii) sp3
C. PCl5 (iii) sp3d2
D. [Pt(NH3)4]2+ (iv) sp3d

  • A    B    C    D

    (iii) (ii)  (iv) (i)

  • A    B    C    D

    (i)  (iv) (ii)  (iii)

  • A    B    C    D

    (iii) (iv) (ii)  (i)

  • A    B    C    D

    (i)  (ii)  (iv) (iii)


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409.

Which of the following statment is true?

  • SnCl4 is more stable than SnCl2

  • PbCl2 is more stable than PbCl4

  • GeCl4, is more stable than GeCl2

  • TICl3 is more stable than TICl


410.

Microcosmic salt when heated strongly, a transparent bead is formed which is used in the identification of

  • ZnO

  • Al2O3

  • MgO

  • SiO2


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