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451.

Excess of PCl5 reacts with conc. H2SO4 giving 

  • chlorosulphonic acid

  • thionyl chloride

  • sulphuryl chloride

  • sulphurous acid


C.

sulphuryl chloride

PCl5 reacts with conc H2SO4 to give sulphuryl chloride by replacing its hydroxyl groups with chlorine atoms.

SO2OH2or H2SO4 + 2PCl5  SO2Cl2Sulphuryl chloride + 2POCl3 +2HCl


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452.

Which is the most easily liquifiable rare gas?

  • Xe

  • Kr

  • Ar

  • Ne


453.

Helium is used in balloons in place of hydrogen because it is

  • incombustible

  • lighter than hydrogen

  • radioactive

  • more abundant than hyrogen


454.

In the brown ring test, the brown colour of the ring is due to

  • ferrous nitrate

  • ferric nitrate

  • a mixture of NO and NO2

  • nitrosoferrous sulphate


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455.

The one which has least iodine value is

  • sunflower oil

  • ginger oil

  • ghee

  • groundnut oil


456.

In which of the following, NH3 is not used?

  • Tolles's reagent

  • Nessler's reagent

  • Group reagent for the analysis of IV group basic radicals

  • Group reagent for the analysis of III group basic radicals


457.

Argon is used

  • in filling airships

  • to obtain low temperature

  • in high temperature welding

  • in radiotherapy for treatment of cancer


458.

The incorrect statement in respect of chromyl chloride test is

  • formation of red vapours

  • formation of lead chromate

  • formation of chromyl chloride

  • liberation of chlorine


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459.

The number of naturally occurring p block elements that are diamagnetic is

  • 18

  • 6

  • 5

  • 7


460.

In Kjeldahl's method, ammonia from 5 g of food neutralizes 30 cm3 of 0.1 N acid. The percentage of nitrogen in the food is

  • 0.84

  • 8.4

  • 16.8

  • 1.68


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