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 Multiple Choice QuestionsMultiple Choice Questions

461.

In Ramsay and Rayleigh's isolation of noble gases from air, the nitrogen of the air is finally converted into

  • NaNO2 only

  • NO and NO2

  • NaNO3 only

  • NaNO2 and NaNO3


462.

A white crystalline salt A reacts with dilute HCl to liberate a suffocating gas B and also forms a yellow precipitate. The gas B turns potassium dichromate acidified with dilute H2SO4 to a green coloured solution C. A, B, C are respectively

  • Na2SO3, SO2, Cr2(SO4)3

  • Na2S2O3, SO2, Cr2(SO4)3

  • Na2SO2 , SO2, Cr2(SO4)3

  • Na2SO4, SO2, Cr2(SO4)3


463.

Molecules of a noble gas do not possess vibrational energy because a noble gas

  • is monoatomic

  • is chemically inert

  • has completely filled shells

  • is diamagnetic


464.

Which of the following is employed in flash tubes in photograph?

  • Ar

  • Ne

  • Kr

  • Xe


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465.

Which one of the following sets of ions represents the collection of isoelectronic species?

  • K+, Cl-, Mg2+, Sc3+

  • Na+, Ca2+, Sc3+, F-

  • K+, Ca2+, Sc3+,Cl-

  • Na+, Mg2+, Al3+, Cl-


C.

K+, Ca2+, Sc3+,Cl-

The number of electrons in these species are

Ions Number of electron
Na+ 11-1=10
Mg2+ 12-2=10
Al3+ 13-3=10
F- 9+1=10
K+ 19-1 = 18
Ca2+ 20-2=18
Sc3+ 21-3=18
Cl- 17+1= 18

Na+, Mg2+, Al3+ and F- are isoelectronic species and each one of which has 10 also K+, Ca2+, Sc3+ and Clare electronic species and each one of which has 18 electrons.


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466.

When formic acid is heated with conc. H2SO4  the gas evolved is

  • Only CO2

  • Only CO2

  • mixture of CO and CO2

  • a mixture of SO2 and CO2


467.

excess of PCl5 reacts with concentrated H2SO4 giving

  • chlorosulphuric acid

  • sulphurous acid

  • sulphury chloride

  • thionyl chloride


468.

The statement that is not correct is

  • Hypophosphorous acid reduces silver nitrate to silver

  • In solid state PCl5 exists as [PCl4]+ [PCl6]-

  • Pure phosphine is non-inflammable

  • Phosphorous acid on heating disproportionates to give metaphosphonic acid and phosphine


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469.

On heating with concentrated NaOH solution in an inert atmosphere of CO2 white phosphorus gives a gas. Which of the following statement is incorrect about the gas?

  • It is less basic than NH3

  • It is more basic than NH3

  • It is highly poisonous and has smell like rotten fish

  • Its solution in water decomposes in the presence of light


470.

MSO4 NH4OH XWhite ExcessNH4OH YH2S Z.Here, M and Z are

  • Cu, ZnS

  • Zn, ZnS

  • Fe, FeS

  • Al, Al2S3


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