Be and Al exhibit diagonal relationship. Which of the following s

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41.

Be and Al exhibit diagonal relationship. Which of the following statements about them is/ are not true?

I. Both react with HCl to liberate H2

II. They are made passive by HNO3

Ill. Their carbides give acetylene on treatment with water

IV. Their oxides are amphoteric

  • III only

  • III and IV

  • I and III

  • I only


A.

III only

Among the given statements, statement III (i.e. option a) is not true. 

Be and Al carbides gives methane on treatment with water. 

Be2C + 4H2O → 2Be(OH)2 + CH4

Al4C3 + 12H2O → 4Al(OH)3 + 3CH4


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42.

Which one of the following on hydrolysis, gives the corresponding metallic hydroxide, H2O2 and O2?

  • Li2O

  • Na2O2

  • NaO2

  • Na2O


43.

The metal that produces red-violet colour in the non-luminous flame is

  • Ba

  • Ag

  • Rb

  • Pb


44.

Which pair of the following chlorides do not impart colour to the flame?

  • BeCl2 and SrCl2

  • BeCl2 and MgCl2

  • CaCl2 and BaCl2

  • BaCl2 and SrCl2


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45.

Sodium peroxide which is a yellow solid, when exposed to air becomes white due to the formation of

  • H2O2

  • NaOH and Na2CO3

  • Na2O

  • NaOH and H2O2


46.

The carbonate that will not decompose on heating is

  • Na2CO3

  • CaCO3

  • BaCO3

  • SrCO3


47.

Thomas slag is referred to as :

  • calcium silicate

  • calcium phosphate

  • barium phosphate

  • strontium silicate


48.

Which one of the following statements is true for all the alkali metals?

  • They react with halogens to give the halides MX

  • Their nitrates decompose on heating to give NO2 and O2

  • Their carbonates decompose on heating to give CO2 and the metal oxide

  • They react with oxygen to give mainly the oxide MO2


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49.

Alkali metals have high oxidation potential and hence, they behave as :

  • oxidizing agents

  • Lewis bases

  • reducing agents

  • electrolytes


50.

The effective component, of bleaching powder............is the of calcium :

  • Cl-

  • OCl-

  • O2-

  • O2Cl-


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