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 Multiple Choice QuestionsMultiple Choice Questions

71.

In photoelectric effect, if the energy required to overcome the attractive forces on the electron, (work functions) of Li, Na and Rb are 2.41 eV, 2.30 eV and 2.09 eV respectively, the work function of 'K could approximately be in eV.

  • 2.52

  • 2.20

  • 2.35

  • 2.01


72.

Na2S2O3 reacts with moist Cl2 to form Na2SO4, HCl and X. Which one of the following is X?

  • H2S

  • SO2

  • SO3

  • S


73.

Heating chloroform with aqueous sodium hydroxide solution forms-

  • sodium acetate

  • sodium oxalate

  • sodium formate

  • chloral


74.

Ni anode is used in the electrolytic extraction of

  • Al

  • Mg

  • Na by Down's process

  • Na by Castner's process


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75.

Which of the following is not correct?

  • LiOH is a weaker base than NaOH.

  • Salts of Be undergo hydrolysis

  • Ca(HCO3)2 is soluble in water.

  • Hydrolysis of beryllium carbide gives acetylene.


76.

Which one of the following elements reduces NaOH to Na?

  • Si

  • Pb

  • C

  • Sn


77.

Assertion (A) : Alkali metals are soft and have low melting and boiling points.

Reason (R) : This is because interatomic bonds are weak.

  • Both (A) and (R) are not true.

  • (A) is true but (R) is not the correct explanation of (A).

  • (A) is true but (R) is false.

  • Both (A) and (R) are true and (R) is the correct explanation of (A).


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78.

Consider the following statements-

I. Cs+ ion is more highly hydrated than other alkali metal ions.

II. Among the alkali metals, only lithium forms a stable, nitride by direct combination with nitrogen.

III. Among the alkali metals Li, Na, K, Rb the metal, Rb has the highest melting point.

IV. Among the alkali metals Li, Na, K, Rb only Li forms peroxide when heated with oxygen.

Select the correct statement is

  • I

  • II

  • III

  • IV


B.

II

Among the given statements, statement II is the correct one. 

Lithium (Li) is the only alkali metal which reacts directly with N2 to give nitride (Li3N) which is much more stable.

6Li + N2 → 2Li3N

Li + H2 700 - 800°C Hydrides

The boiling and melting point of Li are highest among the group 1. These are the anomalous behaviour of Li.


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79.

Which of the following reactions does not involve liberation of oxygen?

  • XeF4 + H2O → 

  • XeF4 + O2F2 → 

  • XeF2 + H2O → 

  • XeF6 + H2O → 


80.

Which one of the following statements is not correct?

  • The hydration enthalpies of alkali metal ions decrease down the group.

  • LIthium halides are some what covalent in nature

  • Alkali metals react with water liberating oxygen gas

  • KO2 is paramagnetic.


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