Born-Haber cycle may be used to calculate

• electronegativity

• mass number

• oxidation number

• electron affinity

The heat of formation for CO₂ (g), H₂O (l) and CH₄ (g) are -400 kJ mol^-1, -280 kJ mol^-1 and -70 kJ mol^-1 respectively. The heat of combustion of CH₄ in kJ mol^-1 is

• 890

• -160

• -890

• -90

C (s) + O₂ (g) → CO₂ (g); $∆$H = -94kcal

2CO (g) + O₂ (g) → 2CO₂ (g); $∆$H = -135 kcal.

The heat of formation of CO (g) is

• -26.4 kcal

• 41.2 kcal

• 26.4 kcal

• 229.2 kcal

The entropy of a perfectly crystalline material is zero at 0°C. This is statement of

• first law of thermodynamics

• second law of thermodynamics

• third law of thermodynamics

• law of conservation of energy

235.

In any chemical reaction, a quantity that decrease to a minimum is

• free energy

• entropy

• temperature

• enthalpy

Given, H₂O (l) → H₂O (g); $∆$H₁ = +43 kJ

H₂O (s) → H₂O (l); $∆$H₂ = +6.05 kJ. Calculate the enthalpy of sublimation of ice.

• 49.75 kJ mol^-1

• 37.65 kJ mol^-1

• 43.7 kJ mol^-1

• 55.23 kJ mol^-1

If standard enthalpies of formation of CaCl (s) (hypothetical) and that of CaCl₂ (s) are -188 J mol^-1 and -795 kJ mol^-1 respectively, calculate the value of standard heat of reaction for the following  disproportionation reaction

2CaCl (s) → CaCl₂ (s) + Ca (s)

• -607 kJ mol^-1

• +607 kJ mol^-1

• -419 kJ mol^-1

• +419 kJ mol^-1

Heat formation of H₂O is -188 kJ/ mol and H₂O₂ is 286 kJ/mol. The enthalpy change for the reaction; 2H₂O₂ → 2H₂O + O₂ is

• 196 kJ

• -196 kJ

• 984 kJ

• -984 kJ

When 1 mole of a gas is heated at constant volume, temperature is raised from 298 K to 308 K. Heat supplied to the gas is 500J. Then, which statement is correct?

• q= -W = 500J : ΔE= 0

• q= W = 500J : ΔE= 0

• q = ΔE= 500J , W= 0

• ΔE = 0; q= W = -500J

If enthaplies of formation for C₂H₂(g), CO₂(g) and H₂O(l) at 25°C and 1atm pressure be 52, -394 and -286kJ mol^-1 respectively, then the enthaply of combustion of C₂H₄(g) will be

• -141.2 kJ mol^-1

• -1412 kJ mol^-1

• + 141.2 kJ mol^-1

• + 1412 kJ mol^-1