Order of hydrolysis for the following : from Chemistry Amines

Previous Year Papers

Download Solved Question Papers Free for Offline Practice and view Solutions Online.

Test Series

Take Zigya Full and Sectional Test Series. Time it out for real assessment and get your results instantly.

Test Yourself

Practice and master your preparation for a specific topic or chapter. Check you scores at the end of the test.
Advertisement

 Multiple Choice QuestionsMultiple Choice Questions

281.

Which of the following fibres is not made up of polyamides ?

  • Wool

  • Natural silk

  • Artificial silk

  • Nylon


282.

The high oxidising power offluorine is due to :

  • high electron affinity

  • high heat of dissociation and low heat of hydration

  • high heat of hydration and low heat of dissociation

  • high heat of hydration and high heat of dissociation


283.

Toluene is nitrated and the resulting product is reduced with tin and hydrochloric acid. The product so obtained is diazotised and thenheated with cuprous bromide. The reaction mixture so formed contains

  • mixture of o- and m-bromotoluenes

  • mixture of o- and p-bromotoluenes

  • mixture of o- and p-dibromobenzenes

  • mixture of o- and p-bromoanilines


284.

Identify the 'C' in the reaction :

RNH2 HNO2 A + B + C

  • NH3

  • O2

  • N2

  • CO2


Advertisement
285.

The reaction of an organic compound with ammonia followed by nitration of the product gives a powerful explosive called ROX.The organic compound is

  • phenol

  • toluene

  • glycerine

  • formaldehyde


286.

CH3Br + KCN (alco.)  X Na + C2H5OHReduction Y

What is Y in the series ?

  • CH3CN

  • C2H5CN

  • C2H5NH2

  • CH3NH2


287.

In the following sequence of the reactions, what is D ?

  • Primary amine

  • An amide

  • Phenyl isocyanate

  • A chain lengthed hydrocarbon


288.

Number of isomeric primary amines obtained from C4H11N are :

  • 3

  • 4

  • 5

  • 6


Advertisement
289.

Which of the following amines will not give N2 gas on treatment with nitrous acid (NaNO2 + HCl)?

  • C2H5NH2

  • CH3NH2

  • (CH3)2CH-NH2

  • All will give N2


Advertisement

290.

Order of hydrolysis for the following :

  • RCOCl

  • RCOOR

  • RCONH2

  • (RCO)2O


A.

RCOCl

In acid derivatives acid chlorides is most reactive , it is vigorously hydrolysed by water .

CH3COCl + H2 CH3COOH + HCl

Acid anhydride is less reactive than acid chlorides .It is hydrolysed slowly by water .

(CH3CO)2O + H2slow 2CH3COOH

The hydrolysis of ethyl acetate in boiling water is slow but inthe presence of acid or alkali the reaction is fast .

CH3CO-OC2H5 + H2H+ CH3COOH + C2H5OH

Amides are hydrolysed by water very slowly .

R-CO||-NH2 + H2H+ R-COOH + NH3

Thus , the correct order of hydrolysis is

RCOCl > (RCO)2O > RCOOR > RCONH2


Advertisement
Advertisement