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121.

The number of sigma (σ) and pi (π) bonds present in 1, 3, 5, 7-octatetraene respectively are

  • 14 and 3

  • 17 and 4

  • 16 and 5

  • 15 and 4


B.

17 and 4

The structure of 1, 3, 5, 7-octatetraene is

Since, each single bond is a σ bond and a double bond consists of one sigma and one pi bond. Therefore, the number of sigma and pi bonds are respectively 17 and 4.


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122.

The molecule that contains only sp2 hybrid carbon atoms is

  • isoprene

  • acrylonitrile

  • but-1-ene

  • 1,3-butadiene


123.

Among the following, the molecule of highest dipole moment is

  • CCl4

  • NH3

  • H2O

  • CHCl3


124.

The incorrectly matched pair, among the following is-

  • BrF5 - Trigonal bipyramidal

  • SF4 - See-saw

  • ClF3 - T-shape

  • NH3 - Trigonal pyramidal


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125.

Which one of the following has the shortest bond length?

  • C - H

  • C - N

  • C - F

  • C - C


126.

Pick out the wrong statement.

  • Nitrogen has the ability to form pπ-pπ bonds with itself

  • Bismuth forms metallic bonds in elemental state

  • Catenation tendency is higher in nitrogen when compared with other elements of the same group

  • Nitrogen has higher first ionization enthalpy when compared with other elements of the same group


127.

The wrong statement about the interstitial compounds is

  • their melting points are lower than those of pure metals

  • they retain metallic conductivity

  • they are chemically inert

  • their bonds are neither ionic non covalent


128.

Which of the following is not correct with respect to bond length of the species? 

  • C2C22-

  • B2+ > B2

  • Li2+ > Li2

  • O2 > O2-


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129.

Substance which is weakly repelled by a magnetic field is

  • O2

  • H2O

  • CrO2

  • Fe3O4


130.

The bonds present in the structure of dichromate ion are

  • four equivalent Cr-O bonds only

  • six equivalent Cr-O bonds and one Cr - O - O bond

  • six equivalent Cr-O bonds and one O-O bond

  • eight equivalent Cr-O bonds


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