Assertion : NF3 is a weaker ligand than N(CH3)3.
Reason : NF3 ionizes to give F- ions in aqueous solution.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false.
If both assertion and reason are false.
C.
If assertion is true but reason is false.
Due to high electronegativity and electron withdrawing nature of F-atom, the lone pair of N-atom in NF3 molecule is not easily available for donation. However, in N(CH3)3, -CH3 group is an electron releasing group, thus lone pair of N-atom in N(CH3)3 molecule can be ligated easily. Except for nitrogen fluoride, all other trihalides hydrolyse in water.
Assertion: All the hydrogen atoms in CH4=C=CH2 lie in one plane.
Reason : All the carbon atoms in its are sp2 hybridized.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false.
If both assertion and reason are false.
Bond dissociation energy of CH4 is 360 kJ/mol and C2H6 is 620 kJ/mol. Then bond dissociation energy of C-C bond is
170 kJ/mol
50 kJ/mol
80 kJ/mol
220 kJ/mol
In BF3, the B - F bond length is 1.30Å, when BF3 is allowed to be treated with Me3N, it forms an adduct, Me3N BF3, the bond length of B - F in the adduct is
greater than 1.30 Å
smaller than 1.30 Å
equal to 1.30 Å
none of these
A double bond connecting two atoms .There is a sharing of :
2 electrons
1 electron
4 electrons
All electrons