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 Multiple Choice QuestionsMultiple Choice Questions

31.

An f-shell containing 6 unpaired electrons can exchange

  • 6 electrons

  • 9 electrons

  • 12 electrons

  • 15 electrons


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32.

Among the elements Ca, Mg, P and Cl, the order of increasing atomic radii is

  • Mg< Ca< Cl< P

  • Cl <P <Mg< Ca

  • P <Cl< Ca< Mg

  • Ca <Mg <P < Cl


B.

Cl <P <Mg< Ca

With increase in the number of electrons in the same shell, the atomic radii decreases due to increase in effective nuclear charge. However, atomic radii increases, as the number of shells increases. Thus, on moving down a group atomic radii increases. The electronic configuration of the given element is

      Mg12 = [Ne] 3s2

       Ca20 = [Ar]4s2

       P15 = [Ne] 3s2 3p2

      Cl17 = [Ne]3s2 3p5

In Mg, P and Cl, the number of electrons are increasing in the same shell, thus the order of their atomic radii is
                          Cl <P < Mg
In Ca, the electron is entering in higher shell, thus, it has the highest atomic radii among the given. Thus, the order of radii is
                         Cl<P <Mg< Ca


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33.

Among the following which one has the highest cation of anion size ratio?

  • Csl

  • CsF

  • LiF

  • NaF


34.

What is the value of electron gain enthalpy of Na if IE1 of Na = 5.1 eV?

  • -5.1 eV

  • -10.2 eV

  • +2.55 eV

  • +10.2eV


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35.

Assertion (A): K, Rb and Cs form superoxides.

Reason (R): The stability of the superoxides increases from 'K' to 'Cs' due to decrease in lattice energy.

The correct answer is

  • Both (A) and (R) are true and (R) is the correct explanation of (A).

  • Both (A) and (R) are true but (R) is not the correct explanation of (A)

  • (A) is true but (R) is not true

  • (A) is not true but (R) is true


36.

Which one of the following order is correct for the first ionisation energies of the elements?

  • B <Be <N < O

  • Be <B <N < O

  • B <Be <O <N

  • B <O <Be <N


37.

The oxidation number of oxygen in KO3, Na2O2 is

  • 3, 2

  • 1, 0

  • 0, 1

  • -0.33, -1


38.

What is the fuel of atomic pile ?

  • Thorium

  • Sodium

  • Uranium

  • Petroleum


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39.

The maximum number of unpaired electrons is present in

  • Fe

  • Cu

  • Co

  • Ni


40.

The pair, that is referred as 'chemical twins' is

  • Ac, Cf

  • Hf, Ta

  • Tc, Re

  • La, Ac


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