The number of d- electrons in Fe2+ (Z = 26) is not equal to the

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 Multiple Choice QuestionsMultiple Choice Questions

211.

Solubility of the alkaline earth's metal sulphates in water decreases in the sequence

  • Mg>Ca>Sr>Ba

  • Ca>Sr>Ba>Mg>

  • Sr>Ca>Mg>Ba

  • Sr>Ca>Mg>Ba

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212.

Which of the following pairs of ions are isoelectronic and isostructural? 

  • CO subscript 3 superscript 2 minus end superscript comma space SO subscript 3 superscript 2 minus end superscript
  • ClO subscript 3 superscript minus comma space CO subscript 3 superscript 2 minus end superscript
  • SO subscript 3 superscript 2 minus end superscript comma NO subscript 3 superscript minus
  • SO subscript 3 superscript 2 minus end superscript comma NO subscript 3 superscript minus
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213.

The number of d- electrons in Fe2+ (Z = 26) is not equal to the number of electrons in which one of the following?

  • S- electronic in Mg (Z=12)

  • p-electrons in Cl( Z=17)

  • d- electrons in Fe (Z=26)

  • d- electrons in Fe (Z=26)


B.

p-electrons in Cl( Z=17)

Electronic configuration of Fe2+ is [Ar]3d6 4s0 
therefore, Number of electrons  = 6
Mg- 1s2 2s2 2p6  (6s electrons)
It matches with the 6d electrons of Fe2+ 
Cl- 1s2 2s2 2p6 3s2 3p5 (11 p electrons)
It does not match with the 6d  electrons of Fe2+
Fe- [Ar] 3d6 4s2 (6d electrons)

It does not match with the 6d electrons of Fe2+
Ne- 1s2 2s2 2p6 3s2 3p 6 (6p electrons)
It matches with the 6d electrons of Fe2+.
Hence, Cl has 11 p electrons which do not match in number with 6d electrons of Fe2+

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214.

which of the following orders of ionic radii is correctly represented?

  • H- > H >H+

  • Na+ >F- >O2-

  • F- > O2->Na+

  • F- > O2->Na+

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215.

Be2+ is isoelectronic with which of the following ions?

  • H+

  • Li+

  • Na+

  • Na+

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216.

Identify the wrong statement in the following.

  • Amongst isoelectronic species, smaller the positive charge on the cation, smaller is the ionic radius

  • Amongst isoelectronic species, greater the negative charge on the anion, larger is the ionic radius

  • Atomic radius of the elements increases as one moves down the first group of the periodic table

  • Atomic radius of the elements increases as one moves down the first group of the periodic table

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217.

Which of the following represents the correct order of increasing electron gain enthalpy with negative sign for the elements O, S, F and Cl?

  • Cl < F < O < S

  • O < S < F< Cl

  • F < S < O < Cl

  • F < S < O < Cl

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218.

Which of the following pairs has the same size? 

  • Fe2+ , Ni2+

  • Zr4+, Ti4+

  • Zr4+, Hf4+

  • Zr4+, Hf4+

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219.

Which one of the following ion has electronic configuration [Ar] 3d6?
(At. no:  Mn = 25, Fe = 26, Co = 27, Ni = 28)

  • Ni3+

  • Mn

  • Fe3+

  • Fe3+

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220.

Among the elements Ca, Mg, P and Cl, the order of increasing atomic radii is 

  • Mg< Ca < Cl < P

  • Cl < P < Mg < Ca

  • P < Cl < Ca < Mg

  • P < Cl < Ca < Mg

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