The decreasing nucleophilicity of the following is:
I. CH3S- II. CH3O-
III. -OH IV. EtO-
II > III > 1V > I
III > IV > I > II
IV > III > I > II
II < I < IV < III
When H2S gas is passed in a metal sulphate solution in presence of NH4OH, a white precipitate is produced. The metal is identified as
Zn
Fe
Pb
Hg
Which of the following electronic configuration represents noble gas?
ns2np6
ns2np5
ns2np4
ns2np3
The correct order of ionisation energy of C, N, O, F is :
F < 0 < N < C
F < N < C < 0
C < N < 0 < F
C < 0 < N < F
For the process ,
X (g) + e- X- (g) ; H = x
and X- (g) X (g) + e- ; H = y
select correct alternate
Ionisation energy of x- (g) is y
Electron affinity of X (g) is x
Electron affinity of X (g) is - y
All of the above
Which of the following reactions does not take place?
BF3 + F- B ...(I)
BF3 + 3F- B ...(II)
AlF3 + 3F- Al ...(III)
Only (I)
Only (II)
Only (III)
Only (I) and (III)
B.
Only (II)
BF3 forms complex halides of the type [B] in which B atom has C.N. 4, it cannot extend its C.N. beyond 4 due to the non-availability of d-orbitals in its configuration. Hence, B ion (sp3d2 hybridisation) is not formed. On the other hand, Al can extend its C.N. beyond 4 due to the availability of d-orbitals in its configuration.