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 Multiple Choice QuestionsMultiple Choice Questions

191.

Which of the following electrolytic solutions has the least specific conductance?

  • 0.02N

  • 0.2 N

  • 2 N

  • 0.002 N


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192.

Hydrogen gas is not liberated when the following metal is added to dil HCl

  • Ag

  • Zn

  • Mg

  • Sn


A.

Ag

The metals, present below hydrogen in the electrochemical series, cannot liberate hydrogen from the dilute acids. Among the given metals only Ag is present below hydrogen in electrochemical series, so it does not evolve hydrogen with dil HCl.

    Ag + dil HCl No reaction


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193.

The standard electrode potential for the half-cell reactions are

Zn2+ + 2e- → Zn; E° = -0.76 V

Fe2+ + 2e- → Fe; E° = 0.44 V

The emf of the cell reaction, Fe2+ + Zn → Zn2+ + Fe is

  • -0.32 V

  • -1.20 V

  • +1.20 V

  • +0.32 V


194.

In the electrolysis of acidulated water, it is desired to obtain 1.12 cc of hydrogen per second under STP condition. The current to be passed is

  • 1.93 A

  • 9.65 A

  • 19.3 A

  • 0.965 A


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195.

The one which decreases with dilution is

  • molar conductance

  • conductance

  • specific conductance

  • equivalent conductance


196.

9.65 C of electric current is passed through fused anhydrous magnesium chloride. The magnesium metal thus, obtained is completely converted into a Grignard reagent. The number of moles of the Grignard reagent obtained is

  • 5 × 10-4

  • 1 × 10-4

  • 5 × 10-5

  • 1 × 10-5


197.

The standard emf of galvanic cell involving 3 moles of electrons in its redox reaction is 0.59 V. The equilibrium constant for the reaction of the cell is

  • 1025

  • 1020

  • 1015

  • 1030


198.

E1, E2 and E3 are the emfs of the following three galvanic cells respectively.

(i) Zn (s) | Zn2+ (0.1 M) || Cu2+ (1M) | Cu (s)

(ii) Zn (s) | Zn2+ (1 M) || Cu2+ (1M) | Cu (s)

(iii) Zn (s) | Zn2+ (1 M) || Cu2+ (0.1M) | Cu (s)

Which one of the following is true?

  • E2 > E1 > E3

  • E1 > E2 > E3

  • E3 > E1 > E2

  • E3 > E2 > E1


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199.

The standard emf of a galvanic cell involving 2 moles of electrons in its redox reaction is 0.59 V. The equilibrium constant for the redox reaction of the cell is

  • 1020

  • 105

  • 10

  • 1010


200.

9.65 C of electric current is passed through fused alyhdrous MgCl2. The magnesium metal thus obtained is completely converted into a Grignard reagent. The number of moles of Grignard reagent obtained is

  • 5 × 10-4

  • 1 × 10-4

  • 5 × 10-5

  • 1 × 10-5


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