The standard electrode potential for the half-cell reactions areZ

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 Multiple Choice QuestionsMultiple Choice Questions

191.

Which of the following electrolytic solutions has the least specific conductance?

  • 0.02N

  • 0.2 N

  • 2 N

  • 0.002 N


192.

Hydrogen gas is not liberated when the following metal is added to dil HCl

  • Ag

  • Zn

  • Mg

  • Sn


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193.

The standard electrode potential for the half-cell reactions are

Zn2+ + 2e- → Zn; E° = -0.76 V

Fe2+ + 2e- → Fe; E° = 0.44 V

The emf of the cell reaction, Fe2+ + Zn → Zn2+ + Fe is

  • -0.32 V

  • -1.20 V

  • +1.20 V

  • +0.32 V


D.

+0.32 V

Zn2+ + 2e- → Zn; E° = -0.76 V

Fe2+ + 2e- → Fe; E° = -0.44 V

Cell reaction is

Fe2+ + Zn  → Zn2+ + Fe

Ecell = Ecathode - Eanode

       = -0.44 - (-0.76)

       = -0.44 + 0.76

       = 0.32 V


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194.

In the electrolysis of acidulated water, it is desired to obtain 1.12 cc of hydrogen per second under STP condition. The current to be passed is

  • 1.93 A

  • 9.65 A

  • 19.3 A

  • 0.965 A


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195.

The one which decreases with dilution is

  • molar conductance

  • conductance

  • specific conductance

  • equivalent conductance


196.

9.65 C of electric current is passed through fused anhydrous magnesium chloride. The magnesium metal thus, obtained is completely converted into a Grignard reagent. The number of moles of the Grignard reagent obtained is

  • 5 × 10-4

  • 1 × 10-4

  • 5 × 10-5

  • 1 × 10-5


197.

The standard emf of galvanic cell involving 3 moles of electrons in its redox reaction is 0.59 V. The equilibrium constant for the reaction of the cell is

  • 1025

  • 1020

  • 1015

  • 1030


198.

E1, E2 and E3 are the emfs of the following three galvanic cells respectively.

(i) Zn (s) | Zn2+ (0.1 M) || Cu2+ (1M) | Cu (s)

(ii) Zn (s) | Zn2+ (1 M) || Cu2+ (1M) | Cu (s)

(iii) Zn (s) | Zn2+ (1 M) || Cu2+ (0.1M) | Cu (s)

Which one of the following is true?

  • E2 > E1 > E3

  • E1 > E2 > E3

  • E3 > E1 > E2

  • E3 > E2 > E1


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199.

The standard emf of a galvanic cell involving 2 moles of electrons in its redox reaction is 0.59 V. The equilibrium constant for the redox reaction of the cell is

  • 1020

  • 105

  • 10

  • 1010


200.

9.65 C of electric current is passed through fused alyhdrous MgCl2. The magnesium metal thus obtained is completely converted into a Grignard reagent. The number of moles of Grignard reagent obtained is

  • 5 × 10-4

  • 1 × 10-4

  • 5 × 10-5

  • 1 × 10-5


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