Which of the following electrolytic solutions has the least specific conductance?
0.02N
0.2 N
2 N
0.002 N
The standard electrode potential for the half-cell reactions are
Zn2+ + 2e- → Zn; E° = -0.76 V
Fe2+ + 2e- → Fe; E° = 0.44 V
The emf of the cell reaction, Fe2+ + Zn → Zn2+ + Fe is
-0.32 V
-1.20 V
+1.20 V
+0.32 V
In the electrolysis of acidulated water, it is desired to obtain 1.12 cc of hydrogen per second under STP condition. The current to be passed is
1.93 A
9.65 A
19.3 A
0.965 A
B.
9.65 A
No. of moles of H2 =
No. of equivalence of hydrogen = = 10-4
No. of Faraday's required = 10-4
Current to be passed in one second = 96500 × 10-4
= 9.65 A
The one which decreases with dilution is
molar conductance
conductance
specific conductance
equivalent conductance
9.65 C of electric current is passed through fused anhydrous magnesium chloride. The magnesium metal thus, obtained is completely converted into a Grignard reagent. The number of moles of the Grignard reagent obtained is
5 × 10-4
1 × 10-4
5 × 10-5
1 × 10-5
The standard emf of galvanic cell involving 3 moles of electrons in its redox reaction is 0.59 V. The equilibrium constant for the reaction of the cell is
1025
1020
1015
1030
E1, E2 and E3 are the emfs of the following three galvanic cells respectively.
(i) Zn (s) | Zn2+ (0.1 M) || Cu2+ (1M) | Cu (s)
(ii) Zn (s) | Zn2+ (1 M) || Cu2+ (1M) | Cu (s)
(iii) Zn (s) | Zn2+ (1 M) || Cu2+ (0.1M) | Cu (s)
Which one of the following is true?
E2 > E1 > E3
E1 > E2 > E3
E3 > E1 > E2
E3 > E2 > E1
The standard emf of a galvanic cell involving 2 moles of electrons in its redox reaction is 0.59 V. The equilibrium constant for the redox reaction of the cell is
1020
105
10
1010
9.65 C of electric current is passed through fused alyhdrous MgCl2. The magnesium metal thus obtained is completely converted into a Grignard reagent. The number of moles of Grignard reagent obtained is
5 × 10-4
1 × 10-4
5 × 10-5
1 × 10-5