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 Multiple Choice QuestionsMultiple Choice Questions

371.

Which of the following is not a Lewis base ?

  • NH3

  • H2O

  • AlCl3

  • None of these


372.

The solubility in water of a sparingly soluble salt AB2 is 1.0 × 10-5 mol L-1. Its solubility product number will be

  • 4 × 10-15

  • 4 × 10-10

  • 1 × 10-15

  • 1 × 10-10


373.

The correct order of increasing basic nature for the bases NH3, CH3NH2 and (CH3)2NH is

  • CH3NH2 < NH3 < (CH3)2NH

  • (CH3)2NH < NH3 < CH3NH2

  • NH3 < CH3NH< (CH3)2NH

  • CH3NH< (CH3)2NH < NH3


374.

The solubility of CaF2 in pure water is 2.3 ×10-6 mol dm-3. Its solubility product will be:

  • 4.8 ×10-18

  • 48.66 ×10-18

  • 4.9 ×10-11

  • 48.66 ×10-15


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375.

Two moles of PCl5 were heated in a closed vessel of 2 L. At equilibrium 40% of PCl5 is  dissociated into PCl3 and Cl2.The,value of equilibrium constant is :

  • 0.53

  • 0.267

  • 2.63

  • 5.3


376.

What is the equilibrium expression for the reaction

P4 (s) + 5O2 (g)  P4O10 (s) ?

  • KcP4O10[P4][O2]5

  • KcP4O105[P4][O2]

  • Kc = [O2]5

  • Kc1[O2]5


377.

The pH value of 1/1000 N-KOH solution is :

  • 3

  • 10-11

  • 2

  • 11


378.

The temperature dependence of rate constant (k) of a chemical reaction is written in terms of Arrhenius equation, k = Ae-E*/ RT. Activation energy (E*) of the reaction can be calculated by plating

  • log k vs 1T

  • log k vs 1log T

  • k vs T

  • k vs 1log T


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379.

The heats of combustion of carbon monoxide at constant pressure and at constant volume at 27°C will differ from one another by :

  • 27 cal

  • 54 cal

  • 300 cal

  • 600 cal


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380.

Microcosmic salt is

  • Na4P2O7

  • Na(NH4)HPO4

  • Na(NH3)HPO4H2O

  • MgNH4PO4


B.

Na(NH4)HPO4

Microcosmic salt is Na(NH4)HPO4. It is white crystalline solid. It is separated by fractional crystallisation.

It is obtained when NH4Cl and Na2HPO4 are dissolved in hot water and cooled.

NH4Cl + Na2HPO4 → Na(NH4)HPO4 + NaCl

It is used for the detection of certain, basic radicals which forms coloured mixed phosphate with NaPO3.

Na(NH4)HPO4  NaPO3 + NH3 + H2O

NaPO3 + CoO → NaCo.PO4


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