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 Multiple Choice QuestionsMultiple Choice Questions

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271.

Find the product for

CH3CH2-O-CH2-CH2-O-CH2-C6H5+ HI (excess)

  • HO-CH2CH2OH, C6H5CH2-I, CH3CH2-I

  • C6H5CH2-OH, CH3CH2-I, I-CH2CH2-OH

  • I-CH2CH2-I, C6H5CH2-I, CH3CH2-OH

  • HO-CH2CH2-OH, C6H5CH2-I, CH3CH2-OH


A.

HO-CH2CH2OH, C6H5CH2-I, CH3CH2-I

Presence of excess of HI favours SN1 mechanism. Therefore, formation of products is controlled by the stability of the carbocation resulting in the cleavage of C - O bond in protonated ether. Thus, the product for given equation are C6H5CH2I, CH3CH2I, HOCH2 - CH2OH.


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272.

SN2 reaction readily occurs in

  • CH3CH2-O-CH3

  • CH3-C(CH3)2-O-CH3

  • CH2=CH-CH2-O-CH3

  • Ph-CH2-O-CH2-CH3


273.

An alkyl halide reacts with alcoholic ammonia in a sealed tube , the product formed will be :

  • a primary amine

  • a secondary amine

  • a tertiary amine

  • a mixture of all the three


274.

The major product of the following reaction is


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275.

The catalyst used in the preparation of an alkyl chloride by the action of dry HCl on an alcohol is :

  • anhydrous AlCl3

  • Fecl3

  • anhydrous ZnCl2

  • Cu


276.

In the reaction ,

R - X Alcoholic KCN B Dilute HCI  B

The product B is :

  • alkyl chloride

  • aldehyde

  • carboxylic acid

  • ketone


277.

CH3CH=CHCH3 + CHCl3 + t-BuOK ➔ A. A is


278.

In which of the following preparations of ether, the configuration about chiral centre is not retained?


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279.

Which ofthe following compounds is not chiral?

  • 1-Chloropentane

  • 2-Chloropentane

  • 1-Chloro-2-methyl pentane

  • 3-Chloro-2-methyl pentane


280.

Which ofthe following molecules will not show optical activity?


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