Williamson's synthesis involves : from Chemistry Haloalkanes and

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 Multiple Choice QuestionsMultiple Choice Questions

281.

Decreasing order of stability of ions is.
(i) CH3 - C+H - CH3

(ii) CH- C+H - OCH3

(iii) CH3 - C+H - COCH3

  • (i) > (ii) > (iii)

  • (ii) > (i) > (iii)

  • (ii) > (iii) > (i)

  • (iii) > (i) > (ii)


282.

Which of these compounds is synthesised by chloral?

  • DDT

  • BHC

  • Chloroform

  • Michlers ketone.


283.

What is B ?


284.

The function of AlCl3, in Friedel-Craft's reaction is to

  • absorb HCl

  • absorb water

  • produce nucleophile

  • produce electrophile.


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285.

Consider the reaction,

The correct explanation is

  • the product is formed due to nucleophilic substitution

  • the product is formed according to Saytzeff's rule

  • conjugated double bond product is formed, due to higher stability because of resonance stabilization

  • (CH3)3CO- is a better leaving group


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286.

Williamson's synthesis involves :

  • SN1 mechanism

  • nucleophilic addition

  • SN2 mechanism

  • SE  mechanism


C.

SN2 mechanism

Williamson's synthesis : A reaction in which sodium or potasium alkoxide is heated with an alkyl halide to give ether by the reaction sample as well as mixed ethers can be prepared .This is an example of nucleophilic substitution and follows SN2 mechanism .

RONa + XR  RORsimple + NaXether

RONa + XR'  R-O-R'mixed ether + NaX


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287.

In one reaction, is treated with CH3CN and then hydrolysed. In another reaction  is treated with ethyl acetate and then hydrolysed.

A and B are


288.

In the following sequence of the reactions, identify the final product.


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289.

Chloropicrin is used as an insecticide and has been used as tear war gas .The chloropicrin is :

  • CH2ClCCl3

  • CCl3NO2

  • CH2(CH3)CH2Cl

  • CHI3


290.

The reagent in Friedel-Craft's reaction is :

  • pyridine

  • RCOCl

  • RCOOH

  • HCl


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