Which one of the following statements about benzyl chloride is incorrect?
It is less reactive than alkyl halides
It can be oxidised to benzaldehyde by boiling with copper nitrate solution
It is a lachrymatory liquid and answers Beilstein's test
It gives a white precipitate with alcoholic silver nitrate
Which cycloalkane has the lowest heat of combustion per CH2 group?
Cyclopropane
Cyclobutane
Cyclopentane
Cyclohexane
D.
Cyclohexane
In cyclopropane the angle strain is maximum. Hence, it is highly strained molecule and consequently most unstable. The angle strain in cyclobutane is less than cyclopropane. Hence, cyclobutane is more stable. This stability mcreases upto 6 membered rings, then decreases from 7 to 11 membered rings and from the 12 membered rings onwards attains the stability of 6 membered ring. Heat of combustion is a method of measuring chemical stability. Hence, cyclohexane has the lowest heat of combustion.
A gas decolourised by KMnO4 solution but gives no precipitate with ammoniacal cuprous chloride is
ethane
methane
ethene
acetylene
The IUPAC name for tertiary butyl iodide is
4-iodo butane
2-iodo butane
1-iodo-3-methyl propane
2-iodo-2-methyl propane