The conditions for aromaticity is :
molecule must have clouds of delocalised electrons
molecule must contain (4n + 2) electrons
both (a) and (b)
None of the above
Allene (C3H4) contains :
one double bond, one triple bond and one single bond
one triple and two double bonds
two triple and one double bond
two double and four single bond
Which of the following is correct number of carbon atom present as the constituent of kerosene oil ?
C10 - C16
C4 - C6
C8 - C16
C12 - C18
Alkyl halides react with dialkyl copper reagents to give
alkenyl halides
alkanes
alkyl copper halides
alkenes
Amongst the following compounds, the optically active alkane having lowest molecular mass is
CH3-CH2-CH2-CH3
CH3-CH2-CH(CH3)-CH3
CH3-CH2-C≡CH
KMnO4 (acidic/alkaline) is not decolourised by
Mohr salt
Oxalic acid
Benzene
Propene
C.
Benzene
The acidic/ alkaline KMnO4 is not decolourised by the aromatic compounds due the delocalisation of electrons in the nucleus.
Aromatic compounds which have = or ≡ bond in the side chain decolourise acidic/ alkaline KMnO4. Benzene does not decolourise the acidic/ alkaline KMnO4 due to the delocalisation of electrons.
While propene decolourised the alkaline KMnO4 due to the presence of = bond. Ferrous ammonium sulphate and oxalic acid decolourised the KMnO4 in acidic medium.
2KMnO4 + 10FeSO4 + 8H2SO4 → K2SO4 + 2MnSO4 + 5Fe2(SO4)3 + 8H2O
2KMnO4 + 5C2H2O4 + 3H2SO4 → K2SO4 + 2MnSO4 + 10CO2 + 8H2O
When acetylene is passed through dil H2SO4, in presence of HgSO4 the compound formed is
ether
acetaldehyde
acetic acid
ketone