If BaCl2,ionizes to an extent of 80% in aqueous solution, the val

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 Multiple Choice QuestionsMultiple Choice Questions

101.

What are the products formed when chlorine is passed through aqueous hypo solution?

  • Na2SO3 + HCl + S

  • Na2SO3 + SO3 + HCl

  • Na2SO4 + HCl + S

  • Na2SO4 + HCl + SO2


102.

The vapour pressure of water at 23°C is 19.8 mm, 0.1 mole of glucose is dissolved in 178.2 g ofwater. What is the vapour pressure (in mm) ofthe resultant solution?

  • 19.0

  • 19.602

  • 19.402

  • 19.202


103.

Assertion (A) : The aqueous solution of CH3COONa is alkaline in nature.

Reason (R) : Acetate ion undergoes anionic hydrolysis.

The correct answer is

  • both (A) and (R) are true and (R) is the correct explanation of (A).

  • both (A) and (R) are true but (R) is not the correct explanation of (A).

  • (A) is true but (R) is not true.

  • A) is not true but (R) is true.


104.

During the depression in freezing point experiment, an equilibrium is established between the molecules of

  • liquid solvent and solid solvent

  • liquid solute and solid solvent

  • liquid solute and solid solute

  • liquid solvent and solid solute


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105.

If BaCl2,ionizes to an extent of 80% in aqueous solution, the value of van't Hoff factor is

  • 2.6

  • 0.4

  • 0.8

  • 2.4


A.

2.6

BaCl21(s)H2O Ba2+0 + 2Cl-01-0.8              0.8            2× 0.8 Inaq. solutioni=No. of moles after reactionInitial number of molesi= 1-0.8 + 0.8 + (2×0.8)1i= 2.6


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106.

X is a non-volatile solute and Y is a volatile solvent. The following vapour pressures are observed by dissolving X in Y.
X/mol L-1 Y/mm of Hg
0.10 p1
0.25 p2
0.01 p3

The correct order of vapour pressures is

  • p1 < p2 <p3

  • p3 < p2 < p1

  • p3 <p1 < p2

  • p2 <p1 <p3


107.

Which one of the followng is an isotonic pair of solutions?

  • 0.15 M NaCl and 0.11 M Na2SO4

  • 0.2 M Urea and 0.1 M Sugar

  • 0.1 M BaCl2 and 0.2 M Urea

  • 0.4 M MgSO4 and 0.1 M NH4Cl


108.

The vapour pressure in mm of Hg, of an aqueous solution obtained by adding 18 g of glucose (C6H12O6) to 180g of water at 100°C is

  • 76.0

  • 7.60

  • 759

  • 752.4


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109.

The weight in grams of a non-volatile solute (mol. wt. 60) to be dissolved in 90 g of water to produce a relative lowering of vapour pressure of 0.02 is

  • 4

  • 8

  • 6

  • 10


110.

The experimentally determined molar mass of a non-volatile solute, BaCl2 in water by Cottrell's method, is

  • equal to the calculated molar mass

  • more than the calculated molar mass

  • less than the calculated molar mass

  • double of the calculated molar mass


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