X is a non-volatile solute and Y is a volatile solvent. The follo

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 Multiple Choice QuestionsMultiple Choice Questions

101.

What are the products formed when chlorine is passed through aqueous hypo solution?

  • Na2SO3 + HCl + S

  • Na2SO3 + SO3 + HCl

  • Na2SO4 + HCl + S

  • Na2SO4 + HCl + SO2


102.

The vapour pressure of water at 23°C is 19.8 mm, 0.1 mole of glucose is dissolved in 178.2 g ofwater. What is the vapour pressure (in mm) ofthe resultant solution?

  • 19.0

  • 19.602

  • 19.402

  • 19.202


103.

Assertion (A) : The aqueous solution of CH3COONa is alkaline in nature.

Reason (R) : Acetate ion undergoes anionic hydrolysis.

The correct answer is

  • both (A) and (R) are true and (R) is the correct explanation of (A).

  • both (A) and (R) are true but (R) is not the correct explanation of (A).

  • (A) is true but (R) is not true.

  • A) is not true but (R) is true.


104.

During the depression in freezing point experiment, an equilibrium is established between the molecules of

  • liquid solvent and solid solvent

  • liquid solute and solid solvent

  • liquid solute and solid solute

  • liquid solvent and solid solute


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105.

If BaCl2,ionizes to an extent of 80% in aqueous solution, the value of van't Hoff factor is

  • 2.6

  • 0.4

  • 0.8

  • 2.4


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106.

X is a non-volatile solute and Y is a volatile solvent. The following vapour pressures are observed by dissolving X in Y.
X/mol L-1 Y/mm of Hg
0.10 p1
0.25 p2
0.01 p3

The correct order of vapour pressures is

  • p1 < p2 <p3

  • p3 < p2 < p1

  • p3 <p1 < p2

  • p2 <p1 <p3


D.

p2 <p1 <p3

When a non-volatile solute is added to a volatile solvent, the solute covers up some of the surface of solvent. Thus, less surface area is available for vaporisation of solvent and hence,
vapour pressure decreases. As the amount of non-volatile solute increases, vapour pressure
decreases accordingly.

The order of concentration of X is
                 0.01 < 0.10 < 0.25

The order of vapour pressure is

                       p2 <p1 <p3


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107.

Which one of the followng is an isotonic pair of solutions?

  • 0.15 M NaCl and 0.11 M Na2SO4

  • 0.2 M Urea and 0.1 M Sugar

  • 0.1 M BaCl2 and 0.2 M Urea

  • 0.4 M MgSO4 and 0.1 M NH4Cl


108.

The vapour pressure in mm of Hg, of an aqueous solution obtained by adding 18 g of glucose (C6H12O6) to 180g of water at 100°C is

  • 76.0

  • 7.60

  • 759

  • 752.4


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109.

The weight in grams of a non-volatile solute (mol. wt. 60) to be dissolved in 90 g of water to produce a relative lowering of vapour pressure of 0.02 is

  • 4

  • 8

  • 6

  • 10


110.

The experimentally determined molar mass of a non-volatile solute, BaCl2 in water by Cottrell's method, is

  • equal to the calculated molar mass

  • more than the calculated molar mass

  • less than the calculated molar mass

  • double of the calculated molar mass


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