The aqueous solution of an unknown sodium salt gives the following reactions.
I. It decolourises a solution of iodine in potassium iodide.
II. It gives white turbidity with dil.HCl solution.
III. It gives a white precipitate with AgNO3 solution which changes colours and finally becomes black on standing.
The unknown sodium salt is
Sodium thiosulphate
sodium bisulphite
sodium sulphite
sodium sulphide
Which of the following would exert maximum osmotic pressure?
Decinormal aluminium sulphate
Decinormal barium chloride
Decinormal sodium chloride
A solution obtained by mixing equal volumes of (b) and (c) and filtering
The vapour pressure of 100g water reduces from 3000 Nm-2 to 2985 Nm-2 when 5g of substance 'X' is dissolved in it. Substance 'X' is
methanol
glucose
carbon dioxide
cannot predict
The solubility of saturated solution of Ag2CrO4 is s mol L-1. What is its solubility product?
4s3
s3
2s3
16s2
Steel is heated to below red heat and then, cooled slowly. The process refers to
hardening
annealing
tempering
nitriding
Which does not give a precipitate with AgNO3 solution?
[Co(NH3)6]Cl3
[Co(NH3)5Cl]Cl2
[Co(NH3)4Cl2]Cl
[Co(NH3)3Cl3]
At 25°C, the dissociation constant of a base, BOH, is 1.0 x 10-12. The concentration of
hydroxyl ions in 0.01 M aqueous solution of the base would be
2.0 x 10-6 mo L-1
1.0 x 10-5 mo L-1
1.0 x 10-6 mo L-1
1.0 x 10-7 mo L-1
What is the correct relationship between the pHs of isomolar solutions of sodium oxide (pH1), sodium sulphide (pH2), sodium selenide (pH3) and sodium telluride (pH4)?
pH1 > pH2 pH3 > pH4
pH1 < pH2 pH3 < pH4
pH1 < pH2 pH3 pH4
pH1 > pH2 pH3 > pH4
D.
pH1 > pH2 pH3 > pH4
The correct order of pH of isomolar solutions is
pH1 > pH2 > pH3 > pH4
sodium oxide > sodium sulphide > sodium selenide > sodium telluride.
This is because, in aqueous solution they are hydrolysed as follows:
Na2O + 2H2O + H2O
Na2S + 2H2O
Na2Se + 2H2O
Na2Te + 2H2O
Therefore, the order of acidic strength is
H2Te > H2Se > H2S > H2O
Since, the pH of basic solution is higher than acidic or least basic solution.