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 Multiple Choice QuestionsMultiple Choice Questions

141.

The statement that is INCORRECT about the interstitial compounds is :

  • they are chemically reactive

  • they have metallic conductivity

  • they have high melting points

  • they are very hard


142.

Consider the bcc unit cells of the solids 1 and 2 with the position of atoms as shown below. The radius of atom B is twice that of atom A. The unit cell edge length is 50% more in solid 2 than in 1. What is the approximate packing efficiency in solid 2?

 

  • 75%

  • 65%

  • 45%

  • 90%


143.

Lithium has a bcc structure. Its density is 530 kg m-3 and its atomic mass is 6.94 g mol-1. Calculate the edge length of a unit cell of lithium metal. (NA = 6.02 x 1023 mol-1).

  • 352pm

  • 527pm

  • 264pm

  • 264pm

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144.

A given metal crystallises out with a cubic structure having edge length of 361 pm. If there are four metal atoms in one unit cell, what is the radius of one atom.

  • 40 pm

  • 127 pm

  • 80 pm

  • 80 pm


B.

127 pm

Given, edge length = 361 pm
Four metal atoms in one unit cell
i.e effective number in unit cell (z) = 4 (given)
therefore,
It is a FCC structure
Face diagonal  = 4r


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145.

If a is the length of the side of a cube, the distance between the body centred atom and one corner atom in  the cube will be

  • fraction numerator 2 over denominator square root of 3 end fraction a
  • fraction numerator 4 over denominator square root of 3 end fraction a
  • fraction numerator square root of 3 over denominator 4 end fraction a
  • fraction numerator square root of 3 over denominator 4 end fraction a
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146.

The number of carbon atoms per unit cell of diamond unit cell is

  • 4

  • 8

  • 6

  • 6

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147.

A metal has a fcc lattice. The edge length of the unit cell is 404 pm. The density of the metal is 2.72 g cm-3. The molar mass of the metal is (NA Avogadro's constant= 6.02 x 1023 mol-1)

  • 40 g mol-1

  • 30 g mol-1

  • 27 g mol-1

  • 27 g mol-1

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148.

Which of the following statements about the interstitial compounds is incorrect?

  • They retain metallic conductivity

  • They are chemically reactive

  • They are much harder than the pure metal

  • They are much harder than the pure metal

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149.

A metal crystallises with a face-centered cubic lattice. The edge of the unit cell is 408 pm. The diameter of the metal atom is

  • 288 pm

  • 408 pm

  • 144 pm

  • 204 pm

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150.

The number of octahedral voids (s) per atom present in a cubic close-packed structure is 

  • 1

  • 3

  • 2

  • 4

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