KMnO4 can be prepared from K2MnO4 as per reactionThe reaction ca

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 Multiple Choice QuestionsMultiple Choice Questions

201.

Which one of the following statements is correct when SO2 is passed through acidified K2Cr2O7 solution?

  • The solution is decolourized

  • SO2 is reduced

  • Green Cr2(SO4)3 is formed

  • The solution turns blue


202.

Because of lanthanoid contraction, of elements which of the following elements have nearly same atomic radii ? (Number in the parenthesis are atomic number).

  • Ti (22) and Zr(40)

  • Zr(40) and Nb (41)

  • Zr (40) and Hf (72)

  • Zr (40) and Hf (72)

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203.

In acidic medium,H2O2 changes Cr2O72- to CrO5 which has two (-O-O-) bonds. Oxidation state of Cr in CrO3 is 

  • +5

  • +3

  • +6

  • +6

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204.

Reason of lanthanoid contraction is

  • negligible Screening effect of 'f' orbitals

  • increasing the nuclear charge

  • decreasing the nuclear charge

  • decreasing the nuclear charge

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205.

Which of the following does not give oxygen on heating?

  • KClO3

  • Zn(ClO3)2

  • K2Cr2O7

  • K2Cr2O7

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206.

Which of the following lanthanoid ions is diamagnetic?
(At. number; Ce =58, Sm =62, Eu =63, Yb = 70)

  • Ce2+

  • Sm2+

  • Eu2+

  • Eu2+

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207.

KMnO4 can be prepared from K2MnO4 as per reaction
3 MnO subscript 4 superscript 2 minus end superscript space plus 2 straight H subscript 2 straight O space rightwards harpoon over leftwards harpoon 2 MnO subscript 4 superscript minus space plus MnO subscript 2 space plus 4 OH to the power of minus
The reaction can go to completion by removing OH- ions by adding

  • HCl

  • KOH

  • CO2

  • CO2


D.

CO2

Since OH- are generated from weak acid (H2O), a weak acid (like CO2) should be used to remove it because of a strong acid (HCl) reverse the reaction, KOH increases the concentration of OH-, thus again shifts the reaction in the backwards side. 
CO2 combines with OH- to give carbonate which is easily removed. 
SO2 reacts with water to give strong acid, so it cannot be used. 

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208.

Which one of the following does not correctly represent the correct order of the property indicated aginst it? 

  • Ti < V<Cr< Mn: increasing number of oxidation states

  • Ti< V<Cr3+<Mn3+ : increasing magnetic moment

  • Ti < V < Cr < Mn : Increasing melting points

  • Ti < V < Cr < Mn : Increasing melting points

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209.

Four successive members of the first series of the transition metals are listed below. For which one of them, the standard potential valueleft parenthesis straight E subscript straight M to the power of 2 plus end exponent divided by straight M end subscript superscript straight o right parenthesis has a positive sign?

  • Co (Z=27)

  • Ni (Z=28)

  • Cu (Z=29)

  • Cu (Z=29)

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210.

The catalytic activity of transition metals and their compounds is ascribed mainly to

  • their magnetic behaviour

  • their unfilled d- orbitals

  • their ability to adopt variable oxidation states

  • their ability to adopt variable oxidation states

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