29.5 mg of an organic compound containing nitrogen was digested

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 Multiple Choice QuestionsMultiple Choice Questions

201.

Which one of the following orders presents the correct sequence of the increasing basic nature of the given oxides?

  • Al2O3 < MgO < Na2O < K2O

  • MgO < K2O < Al2O3 < Na2O

  • Na2O < K2O < MgO < Al2O3

  • Na2O < K2O < MgO < Al2O3

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202.

Which of the following statements regarding sulphur is incorrect?

  • S2 molecule is paramagnetic. 

  • The vapour at 200ºC consists mostly of Srings.

  • At 600ºC the gas mainly consists of S2 molecules. 

  • At 600ºC the gas mainly consists of S2 molecules. 

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203.

The structure of IF7 is

  • square pyramid

  • trigonal bipyramid

  • octahedral

  • octahedral

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204.

Boron cannot form which one of the following anions?

  • BF63-

  • BH4-

  • B(OH)4-

  • B(OH)4-

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205.

29.5 mg of an organic compound containing nitrogen was digested according to Kjeldahl’s method and the evolved ammonia was absorbed in 20 mL of 0.1 M HCl solution. The excess of the acid required 15 mL of 0.1 M NaOH solution for complete neutralization. The percentage of nitrogen in the compound is

  • 59.0

  • 47.4

  • 23.7

  • 23.7


C.

23.7

m moles of HCl = 20 × 0.1 = 2
m moles of NaOH = 15 × 0.1 = 1.5
∴ m moles of HCl that consumed NH3 = 0.5
m moles of NH3 = 0.5
milligrams of N in NH3 = 0.5 × 14 = 7 mg

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206.

Which of the following reactions is an example of a redox reaction?

  • XeF4 + O2F2 → XeF6 + O2

  • XeF2 + PF5 → [XeF]+PF6

  • XeF6 + H2O → XeOF4 + 2HF

  • XeF6 + H2O → XeOF4 + 2HF

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207.

The products obtained when chlorine gas reacts with cold and dilute aqueous NaOH are

  • ClO and ClO3

  • ClO2- and ClO3-

  • Cl and ClO

  • Cl and ClO

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208.

A liquid was mixed with ethanol and a drop of concentrated H2SO4 was added. A compound with a fruity smell was formed. The liquid was:

  • CH3OH

  • HCHO

  • CH3COCH3

  • CH3COCH3

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209.

In which of the following arrangements, the sequence is not strictly according to the property written against it? 

  • CO2< SiO2< SnO2< PbO2: increasing oxidising power

  • HF< HCl < HBr < HI : increasing acid strength

  • NH3< PH3< AsH3< SbH3: increasing basic strength

  • NH3< PH3< AsH3< SbH3: increasing basic strength

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210.

Identify the incorrect statement among the following

  • Ozone reacts with SO2 to give SO3

  • Silicon reacts with NaOH(aq) in the presence of air to give Na2SiO3 and H2O

  • Cl2 reacts with excess of NH3 to give N2 and HCl

  • Cl2 reacts with excess of NH3 to give N2 and HCl

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