Which one of the following molecules contains no pi -bond? from

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 Multiple Choice QuestionsMultiple Choice Questions

551.

The correct bond order in the following species is

  • O22+ > O+2> O2-

  • O22+ < O+2< O2-

  • O22+ > O+2< O2-

  • O22+ > O+2< O2-

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552.

Acidity of diprotic acids in aqueous solutions increases in the order

  • H2S < H2Se< H2Te

  • H2Se <H2S <H2Te

  • H2Te <H2S < H2Se

  • H2Te <H2S < H2Se

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553.

Maximum deviation from ideal gas expected from

  • H2 (g)

  • N2 (g)

  • CH4 (g)

  • CH4 (g)

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554.

Which is the strongest acid in the following?

  • H2SO4

  • HClO3

  • HClO4

  • HClO4

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555.

Identify the correct order of solubility in aqueous medium

  • CuS> ZnS> Na2S

  • ZnS > Na2S> CuS

  • Na2S> CuS> ZnS

  • Na2S> CuS> ZnS

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556.

XeF2 is isostructural with 

  • TeF2

  • ICl-2

  • SbCl3

  • SbCl3

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557.

Which one of the following molecules contains no pi -bond?

  • CO2

  • H2O

  • SO2

  • SO2


B.

H2O

All the molecules have O atom with lone pairs, but in H2O the H atom has no vacant orbital for pi-bonding. That's why it does not have any pi- bond.
 
In all other given molecules, the central atom because of the presence of vacant orbitals is capable to farm Pi- bonds.

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558.

Which of the following is a polar molecule?

  • BF3

  • SF4

  • SiF4

  • SiF4

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559.

Which of the following statements is not valid for oxoacids of phosphorus? 

  • Orthophosphoric acid is used in the manufacture of triple superphosphate

  • Hypophosphorous acid is a diprotic acid
  • All oxoacids contain tetrahedral four coordinated phosphorus

  • All oxoacids contain tetrahedral four coordinated phosphorus

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560.

In Which of the following arrangement, the given sequence is not strictly according to the property indicated against it ? 

  • HF < HCl< HBr < HI : increasing acidic strength

  • H2O < H2S < H2Se < H2Te : increasing pKa values.

  • NH3 < PH3 < AsH3 < SbH : increasing acidic character

  • NH3 < PH3 < AsH3 < SbH : increasing acidic character

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