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 Multiple Choice QuestionsMultiple Choice Questions

291.

Among the following, the pair in which the two species are not isostructural, is

  • SiF4 and SF4

  • IO3- and XeO3

  • BH4- and NH4+

  • PF6- and SF6


292.

The helical structure of protein is stabilized by

  • dipeptide bond

  • hydrogen bonds

  • ether bonds

  • peptide bonds


293.

The dipole moment of HBr is 1.6 × 10-30 cm and inter-atomic spacing is 1 Å. The % ionic character of HBr is

  • 7

  • 10

  • 15

  • 27


294.

The bond angle is smallest in

  • H2O

  • H2S

  • BeCl2

  • N2O


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295.

Valence bond theory of metallic bond was given by

  • Dalton

  • Drudel

  • Fajan

  • Pauling 


D.

Pauling 

Valence bond theory (Resonance theory) of metallic bond was given by pualing (1937). According to this theory, the metallic bonding is essentially covalent in origin and metallic structure exhibits resonance of electro-pair bonds between each atom and its nearest neighbors. In other words, there is a resonance of a large number of canonical forms.


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296.

Which combination of atoms can form a polar covalent bond ?

  • H and N

  • H and Br

  • N and N

  • Na and Br


297.

The bond length of H2+, H2- and H2 are in the following order

  • H2+ > H2 > H2-

  • H2H2+ > H2-

  • H2- > H2 > H2+

  • H2- > H2+ > H2


298.

The correct order of bond length is

  • b > a > c > d

  • a > b > c > d

  • d > c > b > a

  • c > d > b > a


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299.

Consider the following ions:

(i) Ni2+   (ii) Co2+  (iii) Cr2+   (iv) Fe3+

(Given, at. no. Cr = 24, Fe = 26, Co = 27, Ni = 28)

The correct order of magnetic moment of these ions is

  • (i) < (ii) < (iii) < (iv)

  • (iv) < (ii) < (iii) < (i)

  • (i) < (iii) < (ii) < (iv)

  • (iii) < (iv) < (ii) < (i)


300.

Geometry of methyl free radical is

  • pyramidal

  • planar

  • tetrahedral

  • linear


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