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 Multiple Choice QuestionsMultiple Choice Questions

311.

The polypeptides are obtained by assembling the peptide units by

  • ionic bond

  • covalent bond

  • intermolecular H-bonding

  • covalent and H-bonding


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312.

Which one of the following have linear structure?

(I) I3- 

(II) NO2- 

(III) I3+ 

(IV) SO2

(V) N3-

  • I, II and III

  • I and V

  • II, III and IV

  • All of these


B.

I and V

I3- ion is made up of l2 molecule with an I- bonded to it by means of a coordinate bond. There are two bond pairs and three lone pairs. In the outer shell of central atom. To minimise the repulsive forces the three lone pairs occupy the equatorial positions. The ion is therefore, linear in shape with a bond angle of exactly 180°.

Similarly, N3- ion is also linear in shape.


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313.

The dipole moment of HBr is 1.6 × 10-30 cm and inter atomic spacing is 1 Å. The % ionic character of HBr is

  • 7

  • 10

  • 25

  • 27


314.

The bond order of H2- ion is 12. If it has 2 bonding electron, how many antibonding electrons it will have?

  • 4

  • 3

  • 2

  • 1


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315.

Ni2+ ion (Z= 28) contains unpaired electrons

  • 1

  • 2

  • 3

  • 5


316.

A magnetic moment of 1.73 BM will be shown by which one among the following compounds

  • [Cu(NH3)4]2+

  • [Ni(CN)4]2-

  • TiCl4

  • [CoCl6]4-


317.

The bond angle is maximum in PI3,which is

Iodide PI3 AsI3 SbI3
Bond angle 102 100°2' 99°
  • due to small size of P

  • due to more bp-bp repulsion in PI3

  • due to less electronegativity of P

  • None of the above


318.

The shape of [PtCl3(C2H4)]- and the hybridisation of Pt respectively are

  • tetrahedral, sp3

  • trigonal pyramidal, sp3

  • square planar, dsp2

  • square planar, d2sp3


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319.

Among the following compounds both coloured and paramagnetic one is

  • K2Cr2O7

  • VOSO4

  • (NH4)2.[TiCl2]

  • K3[Cu(CN)4]


320.

Which of the following has maximum bond energy?

  • C=C

  • C=O

  • O=O

  • N=O


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