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 Multiple Choice QuestionsMultiple Choice Questions

321.

The number of lone pair(s) of electrons on the central atom is [BrF4]-, XeF6 and [SbCl6]3- are, respectively

  • 2, 1 and 1

  • 2, 1 and 0

  • 2, 0 and 1

  • 1, 0 and 0


322.

The lewis acidity of BF3 is less than BCl3 even though fluorine is more electrongative than chlorine. It is due to

  • stronger 1p (B)-3p(Cl) σ- bonding

  • stronger 2p(B) - 3p(Cl) π-bonding

  • stonger 2p(B) - 2p(F)  σ- bonding

  • stronger 2p(B)- 2p(F) π-bonding


323.

What is the structure of XeF6?

  • Tetrahedral

  • Distorted octahedral

  • Octahedral

  • None of these


324.

The geometry around the central atom in ClF4+ is

  • octahedral

  • trigonal bipyramidal

  • square planar

  • square pyramidal


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325.

The shape of XeO2F2 molecule is

  • trigonal bipyramidal

  • square planar

  • tetrahedral

  • see-saw


326.

In OF2, oxygen has hybridisation of

  • sp3

  • sp2

  • sp

  • None of these


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327.

Amongst NO3-, AsO33-, CO32-, ClO3-, SO32- and BO33-, the non -planar species are

  • NO3-,  CO32- and BO33-

  • ClO3-, SO32- and BO33-

  • CO32-, SO32- and BO33-

  • AsO33-, CO32-and SO32-


B.

ClO3-, SO32- and BO33-

 

Species  Hybridisation  Geometry Number of lone pair
NO3- sp2 Trigonal planar Zero
As33- sp3 Pyramidal One
CO32- sp2 Trigonal planar Zero
ClO3- sp2 Pyramidal One
SO32- sp3 Pyramidal One
BO33- sp3 Pyramidal One

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328.

Intramolecular hydrogen bond is present in

  • water

  • o-nitrophenol

  • p-nitrophenol

  • methylamine


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329.

The molecule C3O2 linear structure. This compound has

  • 2σ and 3π bonds

  • 3σ and 4π bonds

  • 4σ and 4π bonds

  • 3σ and 2π bonds


330.

The structure of XeF2 and NH3 respectively are

  • linear, see-saw

  • bent, see-saw

  • bent, tetrahedral

  • linear, pyramidal


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