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 Multiple Choice QuestionsMultiple Choice Questions

341.

Among the following, the most acidic is :

  • CH3COOH

  • ClCH2COOH

  • Cl2CHCOOH

  • Cl2CHCH2COOH


342.

Among BMe3, BF3, BCl3 and B2H6 which one will be the best Lewis acid ?

  • BCl3

  • BMe3

  • B2H6

  • BF3


343.

Which of the following is not a Lewis base ?

  • NH3

  • H2O

  • AlCl3

  • None of these


344.

The solubility in water of a sparingly soluble salt AB2 is 1.0 × 10-5 mol L-1. Its solubility product number will be

  • 4 × 10-15

  • 4 × 10-10

  • 1 × 10-15

  • 1 × 10-10


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345.

The correct order of increasing basic nature for the bases NH3, CH3NH2 and (CH3)2NH is

  • CH3NH2 < NH3 < (CH3)2NH

  • (CH3)2NH < NH3 < CH3NH2

  • NH3 < CH3NH< (CH3)2NH

  • CH3NH< (CH3)2NH < NH3


346.

The solubility of CaF2 in pure water is 2.3 ×10-6 mol dm-3. Its solubility product will be:

  • 4.8 ×10-18

  • 48.66 ×10-18

  • 4.9 ×10-11

  • 48.66 ×10-15


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347.

Two moles of PCl5 were heated in a closed vessel of 2 L. At equilibrium 40% of PCl5 is  dissociated into PCl3 and Cl2.The,value of equilibrium constant is :

  • 0.53

  • 0.267

  • 2.63

  • 5.3


B.

0.267

Degree of dissociation = 0.4

PCl5a(1-x) PCl3ax + Cl2axa= 2, x= 0.4, V = 2[PCl5] = 2( 1-0.4)2= 0.6 mol/L[PCl3] =2 × 0.42= 0.4 mol/L[Cl2] = 2×0.42= 0.4 mol/LKc = [PCl3] [Cl2] [PCl5]= 0.4 ×0.40.6= 0.267


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348.

What is the equilibrium expression for the reaction

P4 (s) + 5O2 (g)  P4O10 (s) ?

  • KcP4O10[P4][O2]5

  • KcP4O105[P4][O2]

  • Kc = [O2]5

  • Kc1[O2]5


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349.

The pH value of 1/1000 N-KOH solution is :

  • 3

  • 10-11

  • 2

  • 11


350.

The temperature dependence of rate constant (k) of a chemical reaction is written in terms of Arrhenius equation, k = Ae-E*/ RT. Activation energy (E*) of the reaction can be calculated by plating

  • log k vs 1T

  • log k vs 1log T

  • k vs T

  • k vs 1log T


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