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61.

The alkene that will give the same product with HBr in the absence as well as in the presence of peroxide is

  • 2-butene

  • 1-butene

  • propene

  • 2-methylpropene


62.

Chlorination of benzene in the presence of halogen carrier is an example of

  • aromatic nucleophilic substitution

  • aromatic electrophilic substitution

  • aromatic nucleophilic addition

  • aromatic electrophilic addition


63.

For preparing an alkane, a saturated solution of sodium or potassium salt of a carboxylic acid is subjected to

  • hydrolysis

  • electrolysis

  • oxidation

  • hydrogenation


64.

The reaction of  with HBr gives predominantly


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65.

An organic compound with molecular formula C6H12 upon ozonolysis give only acetone as the product. The compound is

  • 2,3-dimethyl-1-butene

  • 3-hexane

  • 2-hexene

  • 2,3-dimethyl-2-butene


66.

Which one of the following carbanions is the least stable?

  • CH3CH2-

  • CH3-

  • (CH3)3C-

  • HC≡C-


67.

An alkene having the molecular formula C9H18 on ozonolysis gives 2, 2-dimethyl propanal and 2-butanone. The alkene is :

  • 2, 2, 2-trimethyl-3-hexene

  • 2, 2, 6-trimethyl-3-hexane

  • 2, 3, 4-trimethyl-2-hexene

  • 2, 2, 4-trimethyl-3-hexene


68.

Observe the following reactions and predict the nature of A and B:

  • A and B both are 

  • A and B both are 

  • A is  and B is 

  • A is  and B is 


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69.

Nitration of aniline in strongly acidic medium, result in the formation of m-nitroaniline also. This is because :

  • amino group is meta orienting during electrophilic substitution reaction

  • nitro group goes always to the meta position irrespective of the substituents

  • nitration of aniline is a nucleophilic substitution reaction in strongly acidic medium

  • in strongly acidic conditions aniline is present as anilinium ion


70.

How many σ and Π bonds are present in toluene?

  • 3Π + 8σ

  • 3Π + 10σ

  • 3Π + 15σ

  • 6Π + 3σ


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