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 Multiple Choice QuestionsMultiple Choice Questions

161.

Different conformations of the same molecule are called

  • isomers

  • epimers

  • enantiomers

  • rotamers


162.

Assertion (A) : NH2 group of aniline is ortho, para directing in electrophilic substitutions.

Reason (R) : -NH2 group stabilises the arenium ion formed by the ortho, para attack of the electrophile.

The correct answer is

  • Both (A) and (R) are correct, (R) is the correct explanation of (A).

  • Both (A) and (R) are correct, (R) is not the correct explanation of (A).

  • (A) is correct, but (R) is not correct.

  • (A) is not correct, but (R) is correct.


163.

In Dumas method, 0.3 g of an organic compound gave 45 mL of nitrogen at STP. The percentage of nitrogen is

  • 16.9

  • 18.7

  • 23.2

  • 29.6


164.

The IUPAC name of the following compound is-

(CH3)2CH-CH=CH-CH=CH(C2H5)-CH3

  • 2, 7-dimethyl-3, 5-nonadiene

  • 2, 7-dimethyl-2-ethylheptadene

  • 2-methyl-7-ethyl-3, 5-octadiene

  • 1, 1-dimethyl-6-ethyl-2, 4-heptadiene


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165.

Ferric ion forms a Prussian blue coloured precipitate due to formation of

  • K4[Fe(CN)6]

  • Fe4[Fe(CN)6]3

  • Fe(CNS)3

  • K3[Fe(CN)6]


B.

Fe4[Fe(CN)6]3

Ferric ion forms a Prussian blue coloured precipitate due to formation of Fe4[Fe(CN)6]3.

4FeCl3 + 3Na4 [Fe(CN)6] → Fe4[Fe(CN)6]3Prussian blue + 12 NaCl


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166.

Which of the following will show geometrical isomerism?

  • 1-butene

  • 2-butene

  • 2-methyl propene

  • Propene


167.

n-propyl alcohol and iso-propyl alcohol are examples of

  • position isomerism

  • chain isomerism

  • tautomerism

  • geometrical isomerism


168.

Optical isomerism is shown by

  • butanol-1

  • butanol-2

  • butene-1

  • butene-2


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169.

The IUPAC name of the following compound is:

  • 7 [β-methyl butyl]; 9 butyl tridecane

  • 3 [β-ethyl butyl]; 9 ethyl tridecane

  • 2 [β-ethyl ethenyl]; 8 propyl decane

  • None of the above


170.

Total number of isomers of C4H10O is

  • 7

  • 4

  • 3

  • 8


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