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 Multiple Choice QuestionsMultiple Choice Questions

221.

Methoxy methane and ethanol are

  • position isomers

  • chain isomers

  • functional isomers

  • optical isomers


222.

An organic compound X is oxidised by using acidified K2Cr2O7. The product obtained reacts with phenyl hydrazine but does not answer silver mirror test. The possible structure of X is

  • CH3CH2OH

  • CH3-CO-CH3

  • (CH3)2CHOH

  • CH3CHO


223.

IUPAC name of (CH3)3CCl is

  • n-butyl chloride

  • 3-chloro butane

  • 2-chloro 2-methyl propane

  • t-butyl chloride


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224.

An organic compound on heating with CuO produces CO2 but no water. The organic compound may be

  • carbon tetrachloride

  • chloroform

  • methane

  • ethyl iodide


A.

carbon tetrachloride

Since, the compound on heating with CuO produced CO2, it contains carbon. Again, it does not produce water, hence it does not contain hydrogen. So, the organic compound is carbon tetrachloride (CCl4).


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225.

Chloroacetic acid is a stronger acid than acetic acid. This can be explained using

  • -M effect

  • - I effect

  • +M effect

  • +I effect


226.

1.2 g of organic compound of Kjeldahlization liberates ammonia which consumes 30 cm3 of 1 N HCl. The percentage of nitrogen in the organic compound is

  • 30

  • 35

  • 46.67

  • 20.8


227.

The yellow precipitate formed during the chromyl chloride test is chemically

  • chromic acid

  • lead chromate

  • lead acetate

  • sodium chromate


228.

Which one of the nitrogen atoms in H2NI - NHII - CO - NH2III is the most nucleophilic?

  • III

  • I

  • II

  • All three nitrogen atoms are equally strong nucleophilic centres


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229.

The maximum number of possible optical isomers in 1-bromo-2-methyl cyclobutane is

  • 4

  • 2

  • 8

  • 16


230.

Which one of the following is the most energetic conformation of cyclohexane?

  • Boat

  • Twisted boat

  • Chair

  • Half-chair


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