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 Multiple Choice QuestionsMultiple Choice Questions

231.

Formic acud is a stronger acid than acetic acid. This can be explained using

  • +M effect

  • -I effect

  • +I effect

  • -M effect


232.

The IUPAC name of 

  • but-3-enoic acid

  • but-1-enoic-acid

  • pent-4-enoic acid

  • prop-2-enoic acid


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233.

Mesomeric effect involves

  • delocalisation of π- electron

  • delocalisation of σ- electron

  • partial displacement of electrons

  • delocalisation of π and σ- electron


A.

delocalisation of π- electron

Resonance or mesomeric effect is defined as, the polarity produced in the molecule by the interaction of two π-bonds or between a π-bond and a lone pair of electrons present on an adjacent atom There are two types of mesomeric effect.+M effect is observed when direction of electron displacement is away from an atom or substituent group attached to the conjugated system eg, - halogen, -OH, —NH2, etc On the other hand,–M effect is observed when the transfer of electrons Is towards the atom or substituent group attached to the conjugted systems, eg, —NO,—COOH etc.


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234.

The IUPAC name of 

  • 2-hydroxy-4-pentanone

  • 2-oxo-4-pentanol

  • 4-keto-2-pentanol

  • 4-hydroxy-2-pentanon


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235.

An oxygen containing organic compound was found to contain 52% carbon and 13% of hydrogen. Its vapour density is 23.The compound reacts with sodium metal to liberate hydrogen. A functional isomer of this compound is

  • ethanal

  • methoxy methane

  • methoxy ethane

  • ethanol


236.

The number of optical isomers of the compound CH3—CHBr—CHBr—COOH is

  • 0

  • 1

  • 3

  • 4


237.

Mesa compounds do not show optical activity because

  • they do not contain chiral carbon atoms

  • they have non-superimposable mirror images

  • they contain plane of symmetry

  • they do not contain plane of symmetry


238.

An aromatic compound 'A' (C7H9N) on reacting with NaNO2/HCl at 0°C forms benzyl alcohol and nitrogen gas. The number of isomers possible for the compound 'A' is

  • 5

  • 7

  • 3

  • 6


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239.

Carbocation as an intermediate is likely to be formed in the reaction

  • Propene + Cl2 hv 2-chloropropane

  • Acetone + HCN -OH acetonecyano hydrin

  • Ethylbromide + aq.KOH  ethyl alcohol

  • Hexane anhy. AlCl3/ HCl 2-methyl pentane


240.

The IUPAC name of 'B' is

  • 3-methylbutan-2-ol

  • 2-methylbutan-3-ol

  • 2-methylbutan-2-ol

  • pentan-2-ol


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