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 Multiple Choice QuestionsMultiple Choice Questions

71.

In the hydrogen atom spectrum, the emission of the least energetic photon takes place during the transition from n = 6 energy level to n = .......... energy level.

  • 1

  • 3

  • 5

  • 4


72.

The threshold frequency of a metal corresponds to the wavelength of x nm. In two separate experiments A and B, incident radiations of wavelengths 1/2x nm and 1/4x nm respectively are used. The ratio of kinetic energy of the released electrons in experiment 'B' to that in experiment 'A' is

  • 1/3

  • 2

  • 4

  • 3


73.

The minimum values of uncertainties involved in the determination of both the position and velocity of a particle respectively are 1 × 10-10 m and 1 × 10-10 ms-1.Then, the mass (in kg) of the particle is

  • 5.270 × 10-15

  • 5.270 × 10-20

  • 5.270 × 10-16

  • 5.270 × 10-10


74.

The number of electrons with azimuthal quantum number l = 1 and l = 2 for Cr in ground state respectively are

  • 12, 5

  • 12, 4

  • 16, 5

  • 16, 4


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75.

In which one of the following, d-d transition involves absorption in the ultraviolet region?

  • [Cu(H2O)4]2+

  • [Ti(H2O)6]3+

  • [Co(NH3)6]3+

  • [Co(CN)6]3-


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76.

The shortest wavelength of the line in hydrogen atomic spectrum of Lyman series when RH = 109678 cm-1 is

  • 1002.7 Å

  • 1215.67 Å

  • 1127.30 Å

  • 911.7 Å


D.

911.7 Å

According to Rydberg's formula-

1λ = RHZ21n12 - 1n22

For hydrogen, Z = 1 and 

For lyman series, n1 = 1 and n2 = ∞ (for shortest wavelength)

On substituting values, we get

1λ = 109678 × 12 × 112 - 12     = 109678 cm-1

λ   = 1109678 cm-1

     = 9.117 × 10-6 cm

     = 911.7 × 10-8 cm

     = 911.7 Å


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77.

Which of the following are isoelectronic species?

(i) NH3

(ii) CH3+

(iii) NH2-

(iv) NH4+

Choose the correct answer from the codes given below.

  • (i), (ii), (iii)

  • (ii), (iii), (iv)

  • (i), (ii), (iv)

  • (i), (iii), (iv)


78.

The ratio of the frequency corresponding to the third line in Lyman series of hydrogen atomic spectrum to that of the first line in Balmer series of Li2+ spectrum is

  • 45

  • 54

  • 43

  • 34


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79.

The number of electrons, neutrons and protons in a species are equal to 10, 8 and 8 respectively. The proper symbol of the species

  • O816

  • O2-816

  • O-816

  • O818


80.

A 600 W mercury lamp emits monochromatic radiation of wavelength 331.3 nm. How many photons are emitted from the lamp per second? (h = 6.626 x 10-34 Js; velocity of light = 3×108 ms-1).

  • 1 × 1019

  • 1 × 1022

  • 1 × 1021

  • 1 × 1023


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