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 Multiple Choice QuestionsMultiple Choice Questions

121.

If the kinetic energy of a particle is reduced to half, de-Broglie wavelength becomes

  • 2 times

  • 12 times

  • 4 times

  • 2 times


122.

In an atom the order of increasing energy of electrons with quantum numbers

(i) n=4, l=1      (ii) n=4, l=0     (iii) n=3, l=2 and (iv) n=3, l=1 is

  • III < I <IV < II

  • II < IV < I<III

  • I <III <II <IV

  • IV< II <III <I


123.

The number of angular and radial nodes of 4d orbital respectively are

  • 3,1

  • 1,2

  • 3,0

  • 2,1


124.

The product of uncertainty in velocity and uncertainty in position of a micro particle of mass 'm' is not less than in which of the following?

  • h × 3πm

  • h3π× m

  • h4π × 1m

  • h4π × m


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125.

2p orbitals have

  • n = 1; l = 2

  • n = 1; l = 0

  • n = 2; l = 1

  • n = 2; l = 0


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126.

Aufbau principle is not satisfied by

  • Cr and Cl

  • Cu and Ag

  • Cr and Mg

  • Cu and Na


B.

Cu and Ag

The electrons presents in the different orbitals of the same subshell can exchange their positions. Each such exchange results in release of energy, called exchange energy and hence, leads to a greater stability. As the number of exchanges that can take place is maximum in the exactly half filled and completely filled arrangements, therefore, exchange energy is maximum and hence, the stability is maximum. 

29Cu - 1s2, 2s2 2p6, 3s2 3p6, 4s1, 3d10

47Ag - 1s2, 2s2 2p6, 3s2 3p6, 4s2, 3d10, 4p6 5s1, 4d10

but Aufbau principle states that electrons are filled in increasing order of energy, hence 4s orbital must be filled first than 3d orbital.

In Cu and Ag both electron first enters in the orbital of lower energy, therefore they does not satisfy Aufbau principle.


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127.

Neutrons are found in atoms of all elements except in

  • chlorine

  • oxygen

  • argon

  • hydrogen


128.

The atomic weight of an element is 39. The number of neutrons in its nucleus is one more than the number of protons. The number of protons, neutrons and electrons-respectively in its atoms would be

  • 19, 20, 19

  • 19, 19, 20

  • 20, 19, 19

  • 20, 19, 20


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129.

The energy and radius of electron present in second orbit of He+ respectively are

  • -109 × 10-18J, 105.8 pm

  • -872 × 10-18 J, 211.6 pm

  • -4.36 × 10-18 J, 52.9 pm

  • -2.18 × 10-18 J, 105.8 pm


130.

Assertion (A): Na+ and Mg2+ ions are isoelectronic but the ionic radius of Na+ is greater than that of Mg2+.

Reason (R): The effective nuclear charge of Na+ ion is less than that of Mg2+ ion.

  • Both (A) and (R) are correct but (R) is not the correct explanation of (A)

  • Both (A) and (R) are correct and (R) is correct explanation of (A).

  • (A) is not correct but (R) is correct.

  • (A) is correct but (R) is not correct.


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