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 Multiple Choice QuestionsMultiple Choice Questions

231.

The radius of which of the following orbit is same as that of the first Bohr's orbit of hydrogen atom?

  • Li2+ (n = 2)

  • Li2+ (n = 3)

  • Be3+ (n = 2)

  • He+ ( n = 2)


232.

Which of the following set of quantum numbers represents the highest energy of an atom?

  • n =3, l=2, m=1, s= +1/2

  • n=4, l=0, m=0, s= -1/2

  • n=3, l=0, m=4, s= +1/2

  • n=3, l=1, m=1, s=+1/2


233.

The number of radial nodes present in 3p orbital is

  • 0

  • 1

  • 2

  • 3


234.

The radiation with maximum frequency is

  • X-ray

  • radio waves

  • UV rays

  • IR rays


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235.

The element with the electronic configuration 1s2 2s22p63s23p63d104s1 is

  • Cu

  • Ca

  • Cr

  • Co


236.

Which of the following electron has minimum energy?

  • n = 4; l = 0; m= 0; s = +12

  • n= 4; l= 1; m = ±1; s = +12

  • n = 5; l = 0; m = 0; s = +12

  • n = 3; l = 2; m = -2; s = +12


237.

How many emission spectral lines are possible when hydrogen atom is excited to nth energy level?

  • n(n+1)2

  • (n+1)2

  • (n-1)n2

  • n24


238.

Which of the following corresponds to the energy of the possible excited state of hydrogen?

  • -13.6 eV

  • 13.6 eV

  • -3.4 eV

  • 3.4 eV


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239.

The correct order of the spin only magnetic moment of metal ions in the following low spin complexes, [V(CN)6]4-, [Fe(CN)6]4-, [Ru(NH3)6]3+ and [Cr(NH3)6]2+ is

  • V2+  > Cr2+ > Ru3+ > Fe2+

  • V2+ > Ru3+ > Cr2+ > Fe2+

  • Cr2+ > V2+ > Ru3+ > Fe2+

  • Cr2+ > Ru3+ > Fe2+ > V2+


A.

V2+  > Cr2+ > Ru3+ > Fe2+

V2+ has d3 configuration of which all the 3 are unpaired electrons.

Cr2+ has d4 configuration. On low spin the 4 electrons are arranged as one pair and 2 unpaired electrons.

Ru3+ has d5 configuration. In low spin the 5 electrons are arranged as 2 pairs and 1 electron remain unpaired.

Fe2+ has d6 configuration. In low spin complex all the six electroms are paired so no unpaired electrons.


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240.

Which one of the following about an electron occupying the 1s orbital in a hydrogen atom is incorrect? (The Bohr radius is represented by a0).

  • The electron can be found at a distance 2a0 from the nucleus.

  • The probability density of finding the electron is maximum at the nucleus.

  • The total energy of the electron is maximum when it is at a distance a0 from the nucleus.

  • The magnitude of the potential energy is double that of its kinetic energy on a an average.


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