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 Multiple Choice QuestionsMultiple Choice Questions

61.

When glycerol is treated with excess of HI, it produces

  • 2-iodopropane

  • allyl iodide

  • propene

  • glycerol triiodide


62.

Which one of the following compounds will be most readily dehydrated?


63.

The alcohol having molecular formula C4H9OH, when shaken with a mixture of anhydrous ZnCl2 and cone. HCl gives an oily layer product after five minutes. The alcohol is

  • H3C-(CH2)3-OH

  • (CH3)2CH-CH2OH

  • (CH3)3C-OH

  • H3C-CH(OH)CH2-CH3


64.

 This reaction is called

  • Reimer-Tiemann reaction

  • Lederer-Manasse reaction

  • Sandmeyer reaction

  • Kolbe's reaction


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65.

Self condensation of two moles of ethyl acetate in the presence of sodium ethoxide after acidification yield

  • acetic acid

  • acetoacetic ester

  • ethyl propionate

  • ethyl butyrate


66.

The formula of ethyl carbinol is

  • CH3OH

  • CH3CH2OH

  • CH3CH2CH2OH

  • (CH3)3COH


67.

Which of the following gives red colour in Victor Meyer's test?

  • n-propyl alcohol

  • Isopropyl alcohol

  • tert-butyl alcohol

  • sec-butyl alcohol


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68.

When p-nitrobromobenzene reacts with sodium ethoxide, the product obtained is

  • p-nitroanisole

  • ethyl phenyl ether

  • p-nitrophenetole

  • no reaction occurs


C.

p-nitrophenetole

In general aryl halides are highly stable and do not take part in Williamson's synthesis, but presence of strong electron withdrawing group like NO2 makes the C-X bond weaker and facilitate the substitution of -Br by -OR.

        


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69.

Hydroboration oxidation of 4-methyl octene would give

  • 4-methyl octanol

  • 2-methyl decane

  • 4-methyl heptanol

  • 4-methyl-2-octanone


70.

When ethyl alcohol is heated with conc. H2SO4, the product obtained is

  • CH3COOC2H5

  • C2H2

  • C2H6

  • C2H4


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